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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wright, Adrian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2011Biocompatibility of magnesium phosphate minerals and their stability under physiological conditionscitations
- 2011Structure and magnetic properties of the cubic oxide fluoride BaFeO2Fcitations
- 2009Influence of cooling rate on the structure and composition of NaxCoO2 (x similar to 0.65)citations
- 2009Fluorination of perovskite-related phases of composition SrFe1-xSnxO3-deltacitations
- 2006Crystal structure and magnetic properties of Ca₂MnAlO₅.₅, an n=3 brownmillerite phasecitations
- 2004Crystallographic and magnetic structures of Y₀.₈Sr₂.₂Mn₂GaO₈-ɗ : a new vacancy-ordered perovskite structurecitations
- 2003Synthesis and Characterisation of the Reduced Double-Layer Manganite Sr₃Mn₂O₆₊xcitations
- 2002Structures & Magnetic Ordering in the BrownMillerite Phases, Sr₂MnGaO₅ and Ca₂MnALO₅citations
- 2002Synthesis and characterisation of reduced single layer manganite Sr₂MnO₃.₅₊xcitations
- 2001Synthesis and structure of Sr₂MnGaO₅, a new layered manganese oxidecitations
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article
Synthesis and characterisation of reduced single layer manganite Sr₂MnO₃.₅₊x
Abstract
The nuclear and magnetic structures of polycrystalline Sr2MnO3.5 have been determined by the Rietveld analysis of neutron powder diffraction data and electron diffraction techniques. The pure Mn3+ single-layered phase crystallizes in the primitive monoclinic space-group Y2(1)/c with lattice constants a = 6.8524(3) Angstrom; b = 10.8131(4) Angstrom; c = 10.8068(4) Angstrom; beta = 113.247(4)degrees. The oxygen defects form an ordered superstructure within the perovskite block layers consisting of interconnected MnO5 square pyramids, slightly different from those observed for the defect perovskites SrMDO2.5 and Ca2MHO3.5. Magnetic susceptibility studies show a broad transition at similar to280K, which is attributed to an overall antiferromagnetic ordering of spins, which leads to doubling of the unit cell along [100]. The magnetic unit cell comprises ferromagnetic clusters of four corner-sharing MnO5 pyramids, which are antiferromagnetically aligned to other similar clusters within the perovskite block layers. (C) 2002 Elsevier Science (USA).