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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Norén, L.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2012Temperature-dependent electrical, elastic and magnetic properties of sol–gel synthesized Bi0.9Ln0.1FeO3Ln = Nd, Sm)citations
- 2006A structure and phase analysis investigation of the "1:1" ordered A2InNbO6 perovskites (A=Ca2+, Sr2+, Ba2+)citations
- 2004A structure, conductivity and dielectric properties investigation of A 3CoNb 2O 9 (A=Ca 2+, Sr 2+, Ba 2+) triple perovskitescitations
- 2001An electron and X-ray diffraction investigation of Ni1+xTe2 and Ni1+xSe2 Cdl2/NiAs type solid solution phasescitations
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article
An electron and X-ray diffraction investigation of Ni1+xTe2 and Ni1+xSe2 Cdl2/NiAs type solid solution phases
Abstract
<p>The reported wide-range nonstoichiometric Ni<sub>1+x</sub>Te<sub>2</sub>, 0 ≤ × ≤0.83, and Ni<sub>1+x</sub>Se<sub>2</sub>, 0.57 ≤×≤0.92, CdI<sub>2</sub>/NiAs structure type solid solution fields have been carefully reinvestigated via electron and X-ray powder diffraction to search for evidence of Ni/vacancy ordering and superstructure phases. In the case of telluride, evidence is thereby found for a Ni<sub>3</sub>Te<sub>4</sub> superstructure phase attempting to condense out at × ̃ 0.5 while, in the case of selenide, three quite distinct phases have been identified within the Ni<sub>1+x</sub>Se<sub>2</sub> solid solution field. An intriguing characteristic honeycomb diffuse-intensity distribution has also been observed across the solid solution field in the case of the Ni<sub>1+x</sub>Te<sub>2</sub> system. Its presence has been attributed to low frequency phonon modes along certain very specific directions of reciprocal space.</p>