| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kraus, Florian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024[Br4F21]− - a unique molecular tetrahedral interhalogen ion containing a μ4-bridging fluorine atom surrounded by BrF5 moleculescitations
- 2022Photochemistry with ClF3 – An Access to [ClOF2]+ Saltscitations
- 2022Bromine Pentafluoride BrF5, the Formation of [BrF6]− Salts, and the Stereochemical (In)activity of the Bromine Lone Pairscitations
- 2021DFT-Guided Crystal Structure Redetermination and Lattice Dynamics of the Intermetallic Actinoid Compound UIrcitations
- 2021Barium bis[tetrafluoridobromate(III)]citations
- 2021Coordination of trivalent lanthanum and cerium, and tetravalent cerium and actinides (An = Th(iv), U(iv), Np(iv)) by a 4-phosphoryl 1H-pyrazol-5-olate ligand in solution and the solid statecitations
- 2021Photochemistry with Chlorine Trifluoride : Syntheses and Characterization of Difluorooxychloronium(V) Hexafluorido(non)metallates(V), [ClOF2][MF6] (M=V, Nb, Ta, Ru, Os, Ir, P, Sb)citations
- 2020Redetermination of the crystal structure of caesium tetrafluoridobromate(III) from single-crystal X-ray diffraction datacitations
- 2020Reactions in Anhydrous Liquid Ammonia : Syntheses and Crystal Structures of [M(NH3)8]I2 (M = Eu, Yb) with Bicapped Trigonal-Prismatic Octaammine Lanthanoid(II) Cations
- 2019Evolutionary Algorithm-Based Crystal Structure Prediction for Copper (I) Fluoridecitations
- 2019Rubidium tetrafluoridobromate(III): redetermination of the crystal structure from single-crystal X-ray diffraction datacitations
- 2019Crystal Structures of α- And β-Nitrogen Trifluoridecitations
- 2019Half-metallicity in uranium intermetallicscitations
- 2019Synthesis and Characterization of [Br 3 ][MF 6 ] (M=Sb, Ir), as well as Quantum Chemical Study of [Br 3 ] + citations
- 2019Reactions of KBrF4 with platinum metalscitations
- 2018Redetermination of the crystal structure of K[BrF4] from single-crystal X-ray diffraction datacitations
- 2012Uranyl Halides from Liquid Ammoniacitations
- 2011The Complex Amide K-2[Zr(NH2)(6)]citations
Places of action
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article
Photochemistry with ClF3 – An Access to [ClOF2]+ Salts
Abstract
Funding Information: We thank Dr. Matthias Conrad and Dr. Sergei Ivlev for helpful discussions and the Deutsche Forschungsgemeinschaft for funding. We thank Solvay for generous donations of F. Open Access funding enabled and organized by Projekt DEAL. 2 Publisher Copyright: © 2022 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH. ; A route to salts of the [ClOF2]+ cation is described that does not require the parent fluoride ClOF3 as a starting material. These can be obtained when either metals such as Cr, Rh, Pd and Au, halides such as PtCl2, SnF2 and PbF4, or oxides such as B2O3, OsO4, GeO2, SnO and Sb2O4 are reacted with ClF3 and additional O2, where necessary, under UV irradiation. Cr, Rh, Pd, PtCl2, GeO2, and SnO formed salts with the respective hexafluoridometallate(IV) anion with the composition [ClOF2]2[MF6]. They crystallize in two distinct structure types in either the monoclinic crystal system (M=Cr, Rh, Ge) or the orthorhombic one (M=Pd, Pt, Sn). The fluorides SnF2 and PbF4 were converted to the monoclinic salts [ClOF2]MF5, and B2O3 formed orthorhombic [ClOF2][BF4]. The triclinic compound ([ClOF2][OsO3F3])2⋅OsF6 was obtained from OsO4 and contains a neutral co-crystallized OsF6 molecule. A monoclinic double salt with the composition [ClOF2]2[AuF4][SbF6] was obtained by reacting a mixture of Sb2O4 and Au. The compounds were investigated by single crystal X-ray diffraction and IR and Raman spectroscopy. Quantum-chemical calculations for the solid-state allowed for the band assignments of the vibrational spectra. ; Peer reviewed