| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Nieger, Martin
University of Helsinki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2022A PH-functionalized dicationic bis(imidazolio)diphosphinecitations
- 2021Small Variations, Big Impact
- 2020A Ditopic Phosphane-decorated Benzenedithiol as Scaffold for Di- and Trinuclear Complexes of Group-10 Metals and Goldcitations
- 2019Synthesis of Functionalized Azobiphenyl‐ and Azoterphenyl‐ Ditopic Linkers: Modular Building Blocks for Photoresponsive Smart Materialscitations
- 2019Reactive intermediates in the reaction of hydrazinecarbothioamides with 2-(bis(methylthio)methylene)malononitrile and ethyl 2-cyano-3,3-bis(methylthio)acrylatecitations
- 2019A Ferrocenophane-Based Diaminophosphenium Ioncitations
- 2018Steric Control in Reactions of N-Heterocyclic Phosphorus Electrophiles with Pentacarbonyl Manganate(-I)citations
- 2017Polylutidinescitations
- 2017Polylutidines: Multifunctional Surfaces through Vapor-Based Polymerization of Substituted Pyridinophanescitations
- 2017Coordination of the ambiphilic phosphinoborane tBu(2)PCH(2)BPh(2) to Cu(I)Clcitations
- 2017Synthesis and Molecular Structures of Ferrocene and Zirconocene Featuring Bis(di(3,5-di-tert.-butyl)phenylphosphino) Groupscitations
- 2017N-Heterocyclic Phosphenium Dihalido-Auratescitations
- 2011Two- and three-dimensional packing diagrams of M(salophen) complexescitations
- 2009Template-controlled assembly of ditopic catechol phosphinescitations
- 2009Spontaneous phosphorus-halogen bond cleavage in N-heterocyclic halogenophosphanes revisitedcitations
- 2009Activation of polarized phosphorus-phosphorus bonds by alkynes
- 2008Pyrido-annellated diazaphospholenes and phospholenium ionscitations
- 2008A phosphanyl-substituted benzo-1,3,2-dioxaborol as ambiphilic bifunctional Lewis Donor-acceptor unitcitations
- 2007Boron templated catechol phosphines as bidentate ligands in silver complexescitations
- 20072-Chloro-1,3,2-diazaphospholenes - a crystal structural studycitations
- 2005Studies on the synthesis, structure and reactivity of heterocyclic metallonitridophosphinatescitations
Places of action
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article
Steric Control in Reactions of N-Heterocyclic Phosphorus Electrophiles with Pentacarbonyl Manganate(-I)
Abstract
<p>Metathesis of Na[Mn(CO)(5)] with N-tBu and N-Mes substituted, electrophilic N-heterocyclic phosphane derivatives afforded in the first case an ionic N-heterocyclic phosphenium (NHP) metalate and in the second case a covalent phosphenium complex. The products were characterized by analytical and spectroscopic data and the NHP complex as well by a single-crystal X-ray diffraction study. A DFT study allows relating the different outcome of the reactions studied with the energetics of the decarbonylation of the appropriate NHP metalates. Closer evaluation reveals steric factors as the key to explaining the observed behavior, and indicates that their impact displays close parallels to NHC chemistry.</p>