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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Daniliuc, Constantin G.
University of Münster
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2023Eutectic Mixtures As Highly Concentrated and Molten Electrolytes with Nearly Single-Ion Conducting Behavior
- 2023An Interesting Conversion Route of Mononuclear Zinc Complex to Zinc Mixed Carboxylate Coordination Polymer
- 2010Synthesis and Structural Characterization of an Isomorphous Series of Bis(imidazolin-2-imine) Metal Dichlorides Containing the First Row Transition Metals Mn, Fe, Co, Ni , Cu, and Zncitations
- 2008Strukturchemie von Kupfer(I)- und Silber(I)-Komplexen mit Triisopropylphosphansulfid-, -selenid- und -tellurid-Liganden ... : Structural Chemistry of Copper(I) and Silver(I) Complexes with Triisopropylphosphane Sulfide, Selenide and Telluride Ligands ...
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article
Synthesis and Structural Characterization of an Isomorphous Series of Bis(imidazolin-2-imine) Metal Dichlorides Containing the First Row Transition Metals Mn, Fe, Co, Ni , Cu, and Zn
Abstract
International audience ; The bis(imidazolin-2-imine) ligand N,N'-bis(1,3-diisopropyl-4,5-dimethylimidazolin-2-ylidene)-1,2-ethanediamine (BLiPr) has been used to synthesize a complete series of transition metal dichloride complexes of the type [(BLiPr)MCl2] with M = Mn, Fe, Co, Ni, Cu, Zn. The molecular structure of each complex was established by X-ray diffraction analysis; the complexes are isomorphous and crystallize in the monoclinic space group C2/c, allowing a comparison of their structural parameters in a constant packing environment. The complexes exhibit distorted tetrahedral geometries around the metal atoms with the dihedral angles between the MN2 and MCl2 planes ranging from 53.9° (M = Cu) to 75.5° (M = Zn).