| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Hampel, Silke
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024ZnO–Graphene Oxide Nanocomposite for Paclitaxel Delivery and Enhanced Toxicity in Breast Cancer Cells
- 2023Facile one-pot hydrothermal synthesis of a zinc oxide/curcumin nanocomposite with enhanced toxic activity against breast cancer cells
- 2020Synthesis of $(Li_{2}Fe_{1–y}Mn_{y})SO$ Antiperovskites with Comprehensive Investigations of $(Li_{2}Fe_{0.5}Mn_{0.5})SO$ as Cathode in Li-ion Batteriescitations
- 2020Filled carbon nanotubes as anode materials for lithium-ion batteriescitations
- 2020Nitrogen-Doped Carbon Nanotube/Polypropylene Composites with Negative Seebeck Coefficient
- 2019Chromium Trihalides CrX3 (X = Cl, Br, I): Direct Deposition of Micro- and Nanosheets on Substrates by Chemical Vapor Transport
- 2018Electro-responsive graphene oxide hydrogels for skin bandages: The outcome of gelatin and trypsin immobilizationcitations
- 2015Mechanical reinforcement of copper films with ceramic nanoparticlescitations
- 2015Recent advances in the synthesis and biomedical applications of nanocomposite hydrogels
- 2014Fabrication of nanoparticle-containing films and nano layers for alloying and joiningcitations
- 2013Loss spectroscopy of molecular solids: combining experiment and theorycitations
- 2010Carbon nanotubes filled with ferromagnetic materials
- 2008Carbon nanotubes filled with a chemotherapeutic agent: a nanocarrier mediates inhibition of tumor cell growthcitations
- 2006Synthesen, Eigenschaften und Kristallstrukturen der Cluster-Salze Bi 6[PtBi6Cl12] und Bi2/3[PtBi 6Cl12]citations
Places of action
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article
Synthesen, Eigenschaften und Kristallstrukturen der Cluster-Salze Bi 6[PtBi6Cl12] und Bi2/3[PtBi 6Cl12]
Abstract
<p>Melting reactions of Bi with Pt and BiCl<sub>3</sub> yield shiny black, air insensitive crystals of the subchlorides Bi<sub>6</sub>[PtBi<sub>6</sub>Cl <sub>12</sub>] and Bi<sub>2/3</sub>[PtBi<sub>6</sub>Cl<sup>12</sup>]. Despite the substantial difference in the bismuth content the two compounds have almost the same pseudo-cubic unit cell and follow the structural principle of a CsCl type cluster salt. Bi<sup>6</sup>[PtBi<sub>6</sub>Cl<sub>12</sub>] consists of cuboctahedral [PtBi<sup>6</sup>Cl<sub>12</sub>]<sup>2-</sup> clusters and Bi<sub>6</sub><sup>2+</sup> polycations (a = 9.052(2) Å, α = 89.88(2)°, space group P1, multiple twins). In the electron precise cluster anion, the Pt atom (18 electron count) centers an octahedron of Bi atoms whose edges are bridged by chlorine atoms. The Bi<sub>6</sub><sup>2+</sup> cation, a nido cluster with 16 skeletal electrons, has the shape of a distorted octahedron with an opened edge. In Bi<sub>2/3</sub>[PtBi<sub>6</sub>Cl<sup>12</sup>] the anion charge is compensated by weakly coordinating Bi<sup>3+</sup> cations which are distributed statistically over two crystallographic positions (a = 9.048(2) Å, α = 90.44(3)°, space group R3̄). Bi <sub>6</sub>[PtBi<sub>6</sub>Cl<sub>12</sub>] is a semiconductor with a band gap of about 0.1 eV. The compound is diamagnetic at room temperature though a small paramagnetic contribution appears towards lower temperature.</p>