| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Krossing, Ingo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Synthesis and characterization of a stable nickelocenium dication saltcitations
- 2022Isolation and characterization of the homoleptic nii and niii bis‐benzene sandwich cationscitations
- 2021Investigations toward a Non-Aqueous Hybrid Redox-Flow Battery with a Manganese-Based Anolyte and Catholytecitations
- 2021Investigations toward a non‐aqueous hybrid redox‐flow battery with a manganese‐based anolyte and catholytecitations
- 2021Fluorination of Ni‐Rich lithium‐ion battery cathode materials by fluorine gas: chemistry, characterization, and electrochemical performance in full‐cellscitations
- 2021Chasing the mond cation: synthesis and characterization of the homoleptic nickel tetracarbonyl cation and its tricarbonyl‐nitrosyl analoguecitations
- 2018Lithium Bis(2,2,2-trifluoroethyl)phosphate Li[O2P(OCH2CF3)2]: a high voltage additive for LNMO/graphite cellscitations
- 2018Synthesis, Characterisation and Reactions of Truly Cationic Ni(I)–Phosphine Complexescitations
- 2015Electrochemical contact separation for PVD aluminum back contact solar cellscitations
- 2014Plating processes on aluminum and application to novel solar cell conceptscitations
- 2007The dielectric response of room-temperature ionic liquids: Effect of cation variationcitations
- 2005Studies on the synthesis, structure and reactivity of heterocyclic metallonitridophosphinatescitations
Places of action
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article
Studies on the synthesis, structure and reactivity of heterocyclic metallonitridophosphinates
Abstract
<p>t-BuP(NH2)(2) reacts with base-stabilized group 13 trihydrides with adduct formation (THF-BH3), with reduction to give t-BuPH2 (Me3N-AlH3) and with elimination of H-2 and formation of a metallonitridophosphinate (Me3N-GaH3). In contrast, the reaction with Cp*TiMe3 proceeds with formation of the four-membered heterocycle [t-Bu(H)P(NH)(2)Ti(Cp*)Me-2]. The aluminonitridophosphinate [t-Bu(H)P(NH)(2)AlMe2](2), reacts with C-H acidic reagents such as ROH, H2O with protonation of the N atom and subsequent formation of t-BuP(NH,),. This general reaction sequence was used for the synthesis of the first alumino(oxo)nitridophosphinate [t-Bu(H)P(NH)OAlMe2](2). The compounds were characterized by spectroscopic methods (H-1, C-13, IR, mass spectrometry) and single crystal X-ray diffraction ([t-Bu(H)P(NH)(2)Ti(Cp*)Me-2], [t-Bu(H)P(NH)OAlMe2](2)).</p>