| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Vahabi, Henri
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (44/44 displayed)
- 2024Fluorinated‐polyhedral oligomeric silsesquioxane (F‐POSS) functionalized halloysite nanotubes (HNTs) as an antifouling additive for epoxy resincitations
- 2024Insights into the Synergistic Effect of Graphene Oxide/Silica Hybrid Nanofiller for Advancing the Properties of Epoxy Resincitations
- 2024Hydrogel and aerogel‐based flame‐retardant polymeric materials: A reviewcitations
- 2024Self-extinguishing epoxy nanocomposites containing industrial biowastes as flame retardant additives
- 2024A sustainable sol-gel approach for the preparation of self-extinguishing hybrid epoxy nanocomposites containing coffee-derived biochar
- 2024Coffee waste-derived biochar as a flame retardant for epoxy nanocompositescitations
- 2023New Transparent Flame-Retardant (FR) Coatings Based on Epoxy-Aluminum Hypophosphite Nanocompositescitations
- 2023New Transparent Flame-Retardant (FR) Coatings Based on Epoxy-Aluminum Hypophosphite Nanocomposites ; Nouveaux revêtements transparents ignifugés (FR) à base de nanocomposites époxy-aluminium hypophosphitecitations
- 2022GTR/Thermoplastics Blends: How Do Interfacial Interactions Govern Processing and Physico-Mechanical Properties?citations
- 2022Novel electrically conductive nanocomposites based on polyaniline and poly(aniline-co-melamine) copolymers grafted on melamine–formaldehyde resincitations
- 2022Flame-retardant natural textiles
- 2021Amine‐functionalized metal–organic frameworks/epoxy nanocomposites: Structure‐properties relationshipscitations
- 2021Green carbon-based nanocomposite biomaterials through the lens of microscopescitations
- 2021Electrospinning for developing flame retardant polymer materials: current status and future perspectivescitations
- 2021Epoxy/Ionic Liquid-Modified Mica Nanocomposites: Network Formation–Network Degradation Correlationcitations
- 2021Corrigendum to “Nonisothermal cure kinetics of epoxy/MnxFe3-xO4 nanocomposites” [Prog. Org. Coat. 140C (2020) 105505]
- 2021Polymer nanocomposites from the flame retardancy viewpoint: A comprehensive classification of nanoparticle performance using the flame retardancy indexcitations
- 2021Correlating the Photophysical Properties with the Cure Index of Epoxy Nanocomposite Coatingscitations
- 2020Halloysite nanotubes (HNTs)/polymer nanocomposites: thermal degradation and flame retardancycitations
- 2020Nanocomposite biomaterials made by 3D printingcitations
- 2020Synthesis, characterization, and high potential of 3D metal–organic framework (MOF) nanoparticles for curing with epoxycitations
- 2020Curing kinetics and thermal stability of epoxy composites containing newly obtained nano-scale aluminum hypophosphite (AlPO2)citations
- 2020Assessment of the protective effect of PMMA on water immersion ageing of flame retarded PLA/PMMA blendscitations
- 2020Calcium carbonate and ammonium polyphosphate flame retardant additives formulated to protect ethylene vinyl acetate copolymer against fire: Hydrated or carbonated calcium?citations
- 2019Biodegradable polyester thin films and coatings in the line of fire: the time of polyhydroxyalkanoate (PHA)?citations
- 2019The Taste of Waste: The Edge of Eggshell Over Calcium Carbonate in Acrylonitrile Butadiene Rubber
- 2019Thermal Stability and Flammability Behavior of Poly(3-hydroxybutyrate) (PHB) Based Compositescitations
- 2019Surface chemistry of halloysite nanotubes controls the curability of low filled epoxy nanocompositescitations
- 2019Novel nanocomposite based on EVA/PHBV/[60]Fullerene with improved thermal propertiescitations
- 2018New polyvinyl chloride (PVC) nanocomposite consisting of aromatic polyamide and chitosan modified ZnO nanoparticles with enhanced thermal stability, low heat release rate and improved mechanical propertiescitations
- 2018Novel poly(amide-azomethine) nanocomposites reinforced with polyacrylic acid- co -2-acrylamido-2-methylpropanesulfonic acid modified LDH: Synthesis and propertiescitations
- 2018Flame retardant epoxy/halloysite nanotubes nanocomposite coatings: Exploring low-concentration threshold for flammability compared to expandable graphite as superior fire retardantcitations
- 2018An attempt to mechanistically explain the viscoelastic behavior of transparent epoxy/starch-modified ZnO nanocomposite coatingscitations
- 2018Acid-aided epoxy-amine curing reaction as reflected in epoxy/Fe3O4 nanocomposites: Chemistry, mechanism, and fracture behaviorcitations
- 2018Hyperbranched poly(ethyleneimine) physically attached to silica nanoparticles to facilitate curing of epoxy nanocomposite coatingscitations
- 2017High-performance hybrid coatings based on diamond-like carbon and copper for carbon steel protectioncitations
- 2017Transparent nanocomposite coatings based on epoxy and layered double hydroxide: Nonisothermal cure kinetics and viscoelastic behavior assessmentscitations
- 2017Transparent nanocomposite coatings based on epoxy and layered double hydroxide: Nonisothermal cure kinetics and viscoelastic behavior assessments
- 2017Epoxy-based flame retardant nanocomposite coatings: Comparison between functions of expandable graphene and halloysite nanotubes
- 2017Continuous-fiber-reinforced thermoplastic composites: influence of processing on fire retardant propertiescitations
- 2017Novel nanocomposites based on poly(ethylene- co -vinyl acetate) for coating applications: The complementary actions of hydroxyapatite, MWCNTs and ammonium polyphosphate on flame retardancycitations
- 2016Flame retardancy of phosphorus-containing ionic liquid based epoxy networkscitations
- 2015Effects of ageing on the fire behaviour of flame-retarded polymers ; a reviewcitations
- 2015Effects of ageing on the fire behaviour of flame-retarded polymers ; Effects of ageing on the fire behaviour of flame-retarded polymers: a reviewcitations
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article
Fluorinated‐polyhedral oligomeric silsesquioxane (F‐POSS) functionalized halloysite nanotubes (HNTs) as an antifouling additive for epoxy resin
Abstract
<jats:title>Abstract</jats:title><jats:sec><jats:label/><jats:p>Antifouling epoxy resin serves as a member of advanced nanocomposite coatings and engineered surfaces. Nevertheless, developing an antifouling epoxy composites is a state‐of‐the‐art technology. Herein, a complex nanostructure is tailored to be served as an advanced additive giving the antifouling characteristics to the epoxy resin. F‐POSS@HNT hybrid nanostructure, that is, halloysite nanotubes (HNTs) decorated with fluorinated polyhedral oligomericsil sesquioxane (F‐POSS), was synthesized and characterized. Chemical structure changes, thermal stability and morphology of hydroxylated HNTs (hHNTs) intermediate and F‐POSS@HNT ultimate nanostructures were analyzed by FTIR spectroscopy, TGA and TEM, respectively. The F‐POSS@HNTs catalyzed the epoxy‐amine crosslinking reaction, taking “<jats:italic>Good</jats:italic>” or “<jats:italic>Excellent</jats:italic>” crosslinking tags an quantified by the “<jats:italic>Cure Index</jats:italic>.” The apparent activation energy values were calculated for the epoxy (reference), epoxy/hHNTs, and epoxy/F‐POSS@HNTs systems (26, 51, and 47 kJ mol<jats:sup>−1</jats:sup>, respectively). Contact angle measurements were performed via dynamic tests demonstrating improved hydro‐ and oleophobicity of the thermoset composites. The advancing contact angle with diiodomethane increased 36% and 30% for nanocomposites containing 5 and 10 wt.% of the developed hybrid nanostructure, respectively, compared with the neat epoxy. Likewise, 54% and 67% reduction in paraffin fouling in the same order confirmed their antifouling ability. Regarding self‐cleaning characteristics, 24% and 33% surface recovery were observed, respectively.</jats:p></jats:sec><jats:sec><jats:title>Highlights</jats:title><jats:p><jats:list list-type="bullet"> <jats:list-item><jats:p>Antifouling surface was achieved in epoxy thermoset nanocomposites for potential industrial applications.</jats:p></jats:list-item> <jats:list-item><jats:p>Self‐cleaning behavior correlated with low wetting and antifouling properties.</jats:p></jats:list-item> <jats:list-item><jats:p>F‐POSS@HNT nanofillers were synthesized and successfully added to epoxy matrix.</jats:p></jats:list-item> <jats:list-item><jats:p>Both hHNT and F‐POSS@HNT showed a beneficial autocatalytic effect on epoxy‐amine reaction yielding satisfactory polymer crosslinking.</jats:p></jats:list-item> <jats:list-item><jats:p>Activation energy was reduced by incorporating F‐POSS@HNT compared with hHNT, signature of facilitated crosslinking.</jats:p></jats:list-item> </jats:list></jats:p></jats:sec>