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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Best, James P.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Tailoring Mechanical Properties and Shear Band Propagation in ZrCu Metallic Glass Nanolaminates Through Chemical Heterogeneities and Interface Densitycitations
- 2024Fracture of the C15 CaAl 2 Laves phase at small length scalescitations
- 2023Segregation-enhanced grain boundary embrittlement of recrystallised tungsten evidenced by site-specific microcantilever fracturecitations
- 2023Application of a nanoindentation-based approach for parameter identification to a crystal plasticity model for bcc metals
- 2021High strain rate in situ micropillar compression of a Zr-based metallic glasscitations
- 2020Relating fracture toughness to micro-pillar compression response for a laser powder bed additive manufactured bulk metallic glasscitations
- 2019Structural periodicity in laser additive manufactured Zr-based bulk metallic glasscitations
- 2019The role of Ga addition on the thermodynamics, kinetics, and tarnishing properties of the Au-Ag-Pd-Cu-Si bulk metallic glass forming systemcitations
- 2019Mechanical anisotropy investigated in the complex SLM-processed Sc- and Zr-modified Al–Mg alloy microstructurecitations
- 2018High temperature impact testing of a thin hard coating using a novel high-frequency in situ micromechanical devicecitations
- 2018Ni nanocluster composites for enhanced impact resistance of multilayered arc-PVD ceramic coatingscitations
- 2017Spectroscopic elucidation of structure-property relations in filaments melt-spun from amorphous polymerscitations
- 2016Small-scale fracture toughness of ceramic thin films: the effects of specimen geometry, ion beam notching and high temperature on chromium nitride toughness evaluationcitations
- 2016Annealing-based electrical tuning of cobalt–carbon deposits grown by focused-electron-beam-induced depositioncitations
- 2016A comparison of three different notching ions for small-scale fracture toughness measurementcitations
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article
Tailoring Mechanical Properties and Shear Band Propagation in ZrCu Metallic Glass Nanolaminates Through Chemical Heterogeneities and Interface Density
Abstract
The design of high-performance structural thin films consistently seeks to achieve a delicate equilibrium by balancing outstanding mechanical properties like yield strength, ductility, and substrate adhesion, which are often mutually exclusive. Metallic glasses (MGs) with their amorphous structure have superior strength, but usually poor ductility with catastrophic failure induced by shear bands (SBs) formation. Herein, we introduce an innovative approach by synthesizing MGs characterized by large and tunable mechanical properties, pioneering a nanoengineering design based on the control of nanoscale chemical/structural heterogeneities. This is realized through a simplified model Zr24Cu76/Zr61Cu39, fully amorphous nanocomposite with controlled nanoscale periodicity (Λ, from 400 down to 5 nm), local chemistry, and glass–glass interfaces, while focusing in-depth on the SB nucleation/propagation processes. The nanolaminates enable a fine control of the mechanical properties, and an onset of crack formation/percolation (>1.9 and 3.3%, respectively) far above the monolithic counterparts. Moreover, we show that SB propagation induces large chemical intermixing, enabling a brittle-to-ductile transition when Λ ≤ 50 nm, reaching remarkably large plastic deformation of 16% in compression and yield strength ≈2 GPa. Overall, the nanoengineered control of local heterogeneities leads to ultimate and tunable mechanical properties opening up a new approach for strong and ductile materials.