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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Eslava, Salvador
Imperial College London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Activating 2D MoS2 by loading 2D Cu–S nanoplatelets for improved visible light photocatalytic hydrogen evolution, drug degradation, and CO2 reductioncitations
- 2024Ca‐doped PrFeO<sub>3</sub> photocathodes with enhanced photoelectrochemical activitycitations
- 2021Structural Evolution of Iron Forming Iron Oxide in a Deep Eutectic-Solvothermal Reactioncitations
- 2021Silver-Decorated TiO2 Inverse Opal Structure for Visible Light-Induced Photocatalytic Degradation of Organic Pollutants and Hydrogen Evolutioncitations
- 2020Silver-Decorated TiO2 Inverse Opal Structure for Visible Light-Induced Photocatalytic Degradation of Organic Pollutants and Hydrogen Evolutioncitations
- 2020Strategies for the deposition of LaFeO3 photocathodescitations
- 2019Graphite-protected CsPbBr3 perovskite photoanodes functionalised with water oxidation catalyst for oxygen evolution in watercitations
- 2019Enhanced Ceria Nanoflakes using Graphene Oxide as a Sacrificial Template for CO Oxidation and Dry Reforming of Methanecitations
- 2019Inexpensive Metal Free Encapsulation Layers Enable Halide Perovskite Based Photoanodes for Water Splitting
- 2019Enhanced ceria nanoflakes using graphene oxide as a sacrificial template for CO oxidation and dry reforming of methanecitations
- 2019Enhanced ceria nanoflakes using graphene oxide as a sacrificial template for CO oxidation and dry reforming of methanecitations
- 2019Strategies for the deposition of LaFeO3 photocathodes:improving the photocurrent with a polymer templatecitations
- 2018Screen printed carbon CsPbBr3 solar cells with high open-circuit photovoltagecitations
- 2018Enhanced Ceria Nanoflakes using Graphene Oxide as a Sacrificial Template for CO Oxidation and Dry Reforming of Methanecitations
- 2018Efficient hematite photoanodes prepared by hydrochloric acid-treated solutions with amphiphilic graft copolymercitations
- 2017A facile way to produce epoxy nanocomposites having excellent thermal conductivity with low contents of reduced graphene oxidecitations
- 2016Autonomous self-healing structural composites with bio-inspired designcitations
- 2015Printing in Three Dimensions with Graphenecitations
- 2013Metal-organic framework ZIF-8 films as low-κ dielectrics in microelectronicscitations
- 2008Reaction of trimethylchlorosilane in spin-on Silicalite-1 zeolite filmcitations
- 2008Nanoporous organosilicate films prepared in acidic conditions using tetraalkylammonium bromide porogenscitations
- 2007Characterization of a molecular sieve coating using ellipsometric porosimetrycitations
- 2007Profile control of novel non-Si gates using B Cl3 N2 plasmacitations
Places of action
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article
Ca‐doped PrFeO<sub>3</sub> photocathodes with enhanced photoelectrochemical activity
Abstract
<jats:p>Perovskite oxides, renowned for their adaptable structure and optoelectronic characteristics, hold significant potential for applications in catalysis and photoelectrochemical processes. This research investigates the preparation of praseodymium iron oxide (PrFeO<jats:sub>3</jats:sub>) by spin coating and the impact of incorporating a calcium (Ca) dopant on its photoelectrochemical efficacy as photocathodes. Spin coating of a polymer containing sol‐gel yielded thin films with uniform morphology and porosity, facilitating effective semiconductor/electrolyte interactions, as characterised by scanning electron microscopy analyses. Evaluation of transient photocurrent responses revealed that introducing Ca at a 5 at% doping level significantly enhanced the photoelectrochemical activity of PrFeO<jats:sub>3</jats:sub>, resulting in an optimal photocurrent of ‐124 µA cm<jats:sup>‐2</jats:sup> at +0.43 V<jats:sub>RHE</jats:sub> under simulated sunlight conditions. This enhancement was accompanied by an incident photon‐to‐current efficiency of 3.8% at +0.43 V<jats:sub>RHE</jats:sub> and 350 nm, along with an onset potential of +1.1 V<jats:sub>RHE</jats:sub>. Ultraviolet and visible spectroscopy analyses indicated an increase in light absorption capabilities in the Ca‐doped films and a noticeable reduction in bandgap compared to the undoped counterparts, further supported by incident photon‐to‐current efficiency measurements. The findings underscore the significant role of dopants in augmenting the photocurrent performance of stable perovskite oxides, highlighting their potential in advancing photon conversion technologies.</jats:p><jats:p>This article is protected by copyright. All rights reserved.</jats:p>