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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Barabash, Anastasiia
Friedrich-Alexander-Universität Erlangen-Nürnberg
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Unveiling the Role of BODIPY Dyes as Small‐Molecule Hole Transport Material in Inverted Planar Perovskite Solar Cellscitations
- 2023Enhancing Planar Inverted Perovskite Solar Cells with Innovative Dumbbell‐Shaped HTMs: A Study of Hexabenzocoronene and Pyrene‐BODIPY‐Triarylamine Derivativescitations
- 2022Highly Stable Lasing from Solution‐Epitaxially Grown Formamidinium‐Lead‐Bromide Micro‐Resonatorscitations
- 2022Shape‐Controlled Solution‐Epitaxial Perovskite Micro‐Crystal Lasers Rivaling Vapor Deposited Onescitations
- 2022Ligand Tuning of Localized Surface Plasmon Resonances in Antimony-Doped Tin Oxide Nanocrystalscitations
- 2022Laser Cutting of Metal‐Halide‐Perovskite Wafers for X‐Ray Detector Integrationcitations
- 2021Characterization of Aerosol Deposited Cesium Lead Tribromide Perovskite Films on Interdigited ITO Electrodescitations
- 2021High‐Throughput Robotic Synthesis and Photoluminescence Characterization of Aqueous Multinary Copper–Silver Indium Chalcogenide Quantum Dotscitations
Places of action
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article
Unveiling the Role of BODIPY Dyes as Small‐Molecule Hole Transport Material in Inverted Planar Perovskite Solar Cells
Abstract
<jats:p>Perovskite solar cells (PSCs) have become a research hotspot since their dramatic increase in power conversion efficiency (PCE), surpassing 26% due to advances in cell engineering and interfacial layers. Within the last factor, hole transporting materials play a crucial role in enhancing device performance and stability. Among several molecular building blocks, BODIPYs are attractive for the design of novel hole transporting material (HTMs) due to their outstanding photophysical and charge transport properties easily tuned by synthetic modifications. Herein, the synthesis of five new BODIPY‐based HTMs <jats:bold>PyBDP 1–5</jats:bold> are reported, functionalized at the meso‐ and α‐ positions with pyrenyl and arylamino units, respectively. The resulting compounds exhibit broad absorption in the visible region, remarkable thermal stability, narrow bandgaps, suitable energy levels, and good hole extraction capability, as subtracted from experimental and computational characterizations. The performance of the BODIPY derivatives as HTMs is evaluated in planar inverted (p‐<jats:italic>i</jats:italic>‐n) PSCs and compared to commonly used PTAA, resulting in highly efficient systems, reaching PCEs very close to that obtained with the reference polymer (21.51%). The incorporation of these BODIPY‐based HTMs result in an outstanding PCE of 20.37% for devices including <jats:bold>PyBDP‐1</jats:bold> and 19.97% for devises containing <jats:bold>PyBDP‐3</jats:bold>, thus demonstrating that BODIPY derivatives are a promising alternative to obtain simple and efficient organic HTMs.</jats:p>