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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bach, Udo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024The balancing act between high electronic and low ionic transport influenced by perovskite grain boundariescitations
- 2024Ester-functionalised polythiophene interlayers for enhanced performance and stability of perovskite solar cellscitations
- 2023Machine Learning Enhanced High‐Throughput Fabrication and Optimization of Quasi‐2D Ruddlesden–Popper Perovskite Solar Cellscitations
- 2022Solution Processable Direct Bandgap Copper‐Silver‐Bismuth Iodide Photovoltaics: Compositional Control of Dimensionality and Optoelectronic Propertiescitations
- 2022Structural and Photophysical-Properties in Guanidinium-Iodide-Treated Perovskite Solar Cellscitations
- 2022Solution processable direct bandgap copper-silver-bismuth iodide photovoltaics : compositional control of dimensionality and optoelectronic propertiescitations
- 2022Back-Contact Perovskite Solar Cell Fabrication via Microsphere Lithographycitations
- 2021Microfluidic Processing of Ligand-Engineered NiO Nanoparticles for Low-Temperature Hole-Transporting Layers in Perovskite Solar Cellscitations
- 2021Can laminated carbon challenge gold? Towards universal, scalable and low-cost carbon electrodes for perovskite solar cellscitations
- 2020A Solution Processed Antireflective Coating for Back-Contact Perovskite Solar Cellscitations
- 2020The Performance-Determining Role of Lewis Bases in Dye-Sensitized Solar Cells Employing Copper-Bisphenanthroline Redox Mediatorscitations
- 2017Polypyridyl Iron Complex as a Hole-Transporting Material for Formamidinium Lead Bromide Perovskite Solar Cellscitations
- 2017Dipole-field-assisted charge extraction in metal-perovskite-metal back-contact solar cellscitations
- 2017A facile deposition method for CuSCN: Exploring the influence of CuSCN on J-V hysteresis in planar perovskite solar cellscitations
- 2016Enhancing the Optoelectronic Performance of Perovskite Solar Cells via a Textured CH3NH3PbI3 Morphologycitations
- 2016Parameters responsible for the degradation of CH3NH3PbI3-based solar cells on polymer substratescitations
- 2016Enhancing the optoelectronic performance of perovskite solar cells via a textured CH3NH3PbI3 morphologycitations
- 2015Screen-Printing of ZnO Nanostructures from Sol-Gel Solutions for Their Application in Dye-Sensitized Solar Cellscitations
- 2014Gas-assisted preparation of lead iodide perovskite films consisting of a monolayer of single crystalline grains for high efficiency planar solar cellscitations
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article
Microfluidic Processing of Ligand-Engineered NiO Nanoparticles for Low-Temperature Hole-Transporting Layers in Perovskite Solar Cells
Abstract
Nickel oxide (NiO) is used as a hole-transporting layer (HTL) in perovskite solar cells (PSCs) because of its high optical transmittance, intrinsic p-type doping, and suitable valence band energy level. However, fabricating high-quality NiO films typically requires high-temperature annealing, which limits their applicability for low-temperature, printable PSCs. Herein, the need for such postprocessing steps is circumvented by coupling 4-hydroxybenzoic acid (HBA) or trimethyloxonium tetrafluoroborate (Me3OBF4) ligand-modified NiO nanoparticles (NPs) with a Tesla-valve microfluidic mixer to deposit high-quality NiO films at a temperature <150 °C. The NP dispersions and the resulting thin films are thoroughly characterized using a combination of optical, structural, thermal, chemical, and electrical methods. While the optical and structural properties of the ligand-exchanged NiO NPs remain comparable with those possessing the native long-chained aliphatic ligands, the ligand-modified NiO thin films exhibit dramatic reductions in surface energy and an increase in hole mobilities. These are correlated with concomitant and significant enhancements in performance and stability factors of PSCs when the ligand-modified NiO NPs are used as HTL layers within p−i−n device architectures.