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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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López-Ortega, Alberto
Universidad Publica de Navarra
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Elucidating individual magnetic contributions in bi-magnetic Fe3O4/Mn3O4 core/shell nanoparticles by polarized powder neutron diffractioncitations
- 2023Elucidating Individual Magnetic Contributions in Bi‐Magnetic Fe3O4/Mn3O4 Core/Shell Nanoparticles by Polarized Powder Neutron Diffractioncitations
- 2019Zinc blende and wurtzite CoO polymorph nanoparticles: rational synthesis and commensurate and incommensurate magnetic ordercitations
- 2018Atomic-scale determination of cation inversion in spinel-based oxide nanoparticlescitations
- 2016Energy Product Enhancement in Imperfectly Exchange-Coupled Nanocomposite Magnetscitations
- 2012Distinguishing the core from the shell in MnO x/MnO y and FeO x/MnO x core/shell nanoparticles through quantitative electron energy loss spectroscopy (EELS) analysiscitations
- 2011Two-, Three-, and four-component magnetic multilayer onion nanoparticles based on iron oxides and manganese oxidescitations
- 2011Role of the oxygen partial pressure in the formation of composite Co-CoO nanoparticles by reactive aggregationcitations
- 2010Synthesis of compositionally graded nanocast NiO/NiCo2O4/Co3O4 mesoporous composites with tunable magnetic propertiescitations
Places of action
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article
Elucidating Individual Magnetic Contributions in Bi‐Magnetic Fe3O4/Mn3O4 Core/Shell Nanoparticles by Polarized Powder Neutron Diffraction
Abstract
Heterogeneous bi‐magnetic nanostructured systems have had a sustained interest during the last decades owing to their unique magnetic properties and the wide range of derived potential applications. However, elucidating the details of their magnetic properties can be rather complex. Here, a comprehensive study of Fe3O4/Mn3O4 core/shell nanoparticles using polarized neutron powder diffraction, which allows disentangling the magnetic contributions of each of the components, is presented. The results show that while at low fields the Fe3O4 and Mn3O4 magnetic moments averaged over the unit cell are antiferromagnetically coupled, at high fields, they orient parallel to each other. This magnetic reorientation of the Mn3O4 shell moments is associated with a gradual evolution with the applied field of the local magnetic susceptibility from anisotropic to isotropic. Additionally, the magnetic coherence length of the Fe3O4 cores shows some unusual field dependence due to the competition between the antiferromagnetic interface interaction and the Zeeman energies. The results demonstrate the great potential of the quantitative analysis of polarized neutron powder diffraction for the study of complex multiphase magnetic materials.