| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Cseri, Levente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Tunable 2D Conjugated Porous Organic Polymer Films for Precise Molecular Nanofiltration and Optoelectronicscitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2020Metal–Organic Frameworks (MOFs) and MOF-Derived Porous Carbon Materials for Sustainable Adsorptive Wastewater Treatment
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2018Robust Covalently Crosslinked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Robust Covalently Cross-linked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
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article
Tunable 2D Conjugated Porous Organic Polymer Films for Precise Molecular Nanofiltration and Optoelectronics
Abstract
<jats:title>Abstract</jats:title><jats:p>Structural design of 2D conjugated porous organic polymer films (2D CPOPs), by tuning linkage chemistries and pore sizes, provides great adaptability for various applications, including membrane separation. Here, four free‐standing 2D CPOP films of imine‐ or hydrazone‐linked polymers (ILP/HLP) in combination with benzene (B‐ILP/HLP) and triphenylbenzene (TPB‐ILP/HLP) aromatic cores are synthesized. The anisotropic disordered films, composed of polymeric layered structures, can be exfoliated into ultrathin 2D‐nanosheets with layer‐dependent electrical properties. The bulk CPOP films exhibit structure‐dependent optical properties, triboelectric nanogenerator output, and robust mechanical properties, rivaling previously reported 2D polymers and porous materials. The exfoliation energies of the 2D CPOPs and their mechanical behavior at the molecular level are investigated using density function theory (DFT) and molecular dynamics (MD) simulations, respectively. Exploiting the structural tunability, the comparative organic solvent nanofiltration (OSN) performance of six membranes having different pore sizes and linkages to yield valuable trends in molecular weight selectivity is investigated. Interestingly, the OSN performances follow the predicted transport modeling values based on theoretical pore size calculations, signifying the existence of permanent porosity in these materials. The membranes exhibit excellent stability in organic solvents at high pressures devoid of any structural deformations, revealing their potential in practical OSN applications.</jats:p>