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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lorenzi, Roberto
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Host–Guest Interactions and Transport Mechanism in Poly(vinylidene fluoride)-Based Quasi-Solid Electrolytes for Lithium Metal Batteriescitations
- 2024On the Origin of the Light Yield Enhancement in Polymeric Composite Scintillators Loaded with Dense Nanoparticlescitations
- 2024PVDF‐HFP Based, Quasi‐Solid Nanocomposite Electrolytes for Lithium Metal Batteriescitations
- 2023Lignin-derived bimetallic platinum group metal-free oxygen reduction reaction electrocatalysts for acid and alkaline fuel cellscitations
- 2023Layered Y3Al5O12:Pr/Gd3(Ga,Al)5O12:Ce optical ceramics: Synthesis and photo-physical propertiescitations
- 2023Highly Reversible Ti/Sn Oxide Nanocomposite Electrodes for Lithium Ion Batteries Obtained by Oxidation of Ti<sub>3</sub>Al<sub>(1‐x)</sub>Sn<sub>x</sub>C<sub>2</sub> Phasescitations
- 2022Unveiling the Role of PEO-Capped TiO2 Nanofiller in Stabilizing the Anode Interface in Lithium Metal Batteriescitations
- 2022Promising Electrocatalytic Water and Methanol Oxidation Reaction Activity by Nickel Doped Hematite/Surface Oxidized Carbon Nanotubes Composite Structurescitations
- 2021Crystallization processes of spinel-like gallium oxide nanocrystals in germano-silicate bulk glassceramics and thin films
- 2021Lenticular Ga-oxide nanostructures in thin amorphous germanosilicate layers - Size control and dimensional constraintscitations
- 2019Responsive charge transport in wide-band-gap oxide films of nanostructured amorphous alkali-gallium-germanosilicatecitations
- 2016Hafnium dioxide luminescent nanoparticles: structure and emission control through doping and thermal treatments
- 2015Energy transfer process between γ-Ga2O3 nanocrystals and Gd3+ ions in nanostructured germano-silicate glassceramic.
- 2012Structural rearrangement at the yttrium-depleted surface of HCl-processed yttrium aluminosilicate glass for 90Y-microsphere brachytherapycitations
- 2012Microfluorescence Analysis of Nanostructuring Inhomogeneity in Optical Fibers with Embedded Gallium Oxide Nanocrystalscitations
- 2012SnO2:Snox core-shell QD in glass: charge transport and UV emission in fully inorganic electroluminescent devices
- 2010Electrically tunable dielectric function in glass with tree like percolating pathways of chargeable conductive nanoparticles
- 2009Electric field induced structural modification and second order optical nonlinearity in potassium niobium silicate glasscitations
- 2007Efficient 1.53 mu m erbium light emission in heavily Er-doped titania-modified aluminium tellurite glassescitations
Places of action
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article
PVDF‐HFP Based, Quasi‐Solid Nanocomposite Electrolytes for Lithium Metal Batteries
Abstract
<jats:title>Abstract</jats:title><jats:p>Composite polymer electrolytes are systems of choice for future solid‐state lithium metal batteries (LMBs). Poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP) is among the most interesting matrices to develop new generation quasi‐solid electrolytes (QSEs). Here it is reported on nanocomposites made of PVDF‐HFP and pegylated SiO<jats:sub>2</jats:sub> nanoparticles. Silica‐based hybrid nanofillers are obtained by grafting chains of poly(ethylene glycol) methyl ether (PEG) with different molecular weight on the surface of silica nanoparticles. The functionalized nanofiller improves the mechanical, transport and electrochemical properties of the QSEs, which show good ionic conductivity values and high resistance against dendrite penetration, ensuring boosted long and safe device operation. The most promising result is obtained by dispersing 5 wt% of SiO<jats:sub>2</jats:sub> functionalized with short PEG chains (PEG<jats:sub>750</jats:sub>, Mw = 750 g mol<jats:sup>−1</jats:sup>) in the PVDF‐HFP matrix with an ease solvent‐casting procedure. It shows ionic conductivity of 0.1 mS cm<jats:sup>−1</jats:sup> at 25 °C, more than 250 h resistance to stripping/plating, and impressive results during cycling tests in LMB with LiFePO<jats:sub>4</jats:sub> cathode.</jats:p>