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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mustarelli, Piercarlo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Host–Guest Interactions and Transport Mechanism in Poly(vinylidene fluoride)-Based Quasi-Solid Electrolytes for Lithium Metal Batteriescitations
- 2024PVDF‐HFP Based, Quasi‐Solid Nanocomposite Electrolytes for Lithium Metal Batteriescitations
- 2022The Electrical Response of Real Dielectrics: Using the Voltage Ramp Method as a Straightforward Diagnostic Tool for Polymeric Composites
- 2022Unveiling the Role of PEO-Capped TiO2 Nanofiller in Stabilizing the Anode Interface in Lithium Metal Batteriescitations
- 2020Polymer-in-Ceramic Nanocomposite Solid Electrolyte for Lithium Metal Batteries Encompassing PEO-Grafted TiO<sub>2</sub> Nanocrystalscitations
- 2020Polymer-in-Ceramic Nanocomposite Solid Electrolyte for Lithium Metal Batteries Encompassing PEO-Grafted TiO2 Nanocrystalscitations
- 2015Ion dynamics and mechanical properties of sulfonated polybenzimidazole membranes for high-temperature proton exchange membrane fuel cellscitations
- 2015ZrO2/PEG hybrid nanocomposites synthesized via sol–gel: Characterization and evaluation of the magnetic propertiescitations
- 2015Facile and green assembly of nanocomposite membranes for fuel cellscitations
- 2014A theoretical approach to evaluate the rate capability of Li-ion battery cathode materialscitations
- 2014Mechanochemical Synthesis of Bumetanide–4-Aminobenzoic Acid Molecular Cocrystals: A Facile and Green Approach to Drug Optimizationcitations
- 2014Mechanism of Low-Temperature Protonic Conductivity in Bulk, High Density, Nanometric Titanium Oxidecitations
- 2014Innovative high performing metal organic framework (MOF)-laden nanocomposite polymer electrolytes for all-solid-state lithium batteriescitations
- 2014Fabrication and electrochemical characterization of amorphous lithium iron silicate thin films as positive electrodes for lithium batteriescitations
- 2013Flexible deposition of TiO2 electrodes for photocatalytic applications: Modulation of the crystal phase as a function of the layer thicknesscitations
- 2013Polymorphism and magnetic properties of Li2MSiO4 (M = Fe, Mn) cathode materialscitations
- 2013Polymorphism and magnetic properties of Li2MSiO4 (M = Fe, Mn) cathode materialcitations
- 2011Increasing the antibacterial effect of lysozyme byimmobilization on multiwalled carbon nanotubes.citations
- 2011Bone reconstruction: Au nanocomposite bioglasses with antibacterial propertiescitations
- 2010Lithium ion conducting PVdF-HFP composite gel electrolytes based on N-methoxyethyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)-imide ionic liquid
- 2009SiO2-P2O5-CaO glasses and glass-ceramics with and without ZnO: relationships among composition, microstructure, and bioactivitycitations
- 2005Synthesis and characterization of Ce0.8Gd0.2O2-y polycrystalline and thin film materials
Places of action
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article
PVDF‐HFP Based, Quasi‐Solid Nanocomposite Electrolytes for Lithium Metal Batteries
Abstract
<jats:title>Abstract</jats:title><jats:p>Composite polymer electrolytes are systems of choice for future solid‐state lithium metal batteries (LMBs). Poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP) is among the most interesting matrices to develop new generation quasi‐solid electrolytes (QSEs). Here it is reported on nanocomposites made of PVDF‐HFP and pegylated SiO<jats:sub>2</jats:sub> nanoparticles. Silica‐based hybrid nanofillers are obtained by grafting chains of poly(ethylene glycol) methyl ether (PEG) with different molecular weight on the surface of silica nanoparticles. The functionalized nanofiller improves the mechanical, transport and electrochemical properties of the QSEs, which show good ionic conductivity values and high resistance against dendrite penetration, ensuring boosted long and safe device operation. The most promising result is obtained by dispersing 5 wt% of SiO<jats:sub>2</jats:sub> functionalized with short PEG chains (PEG<jats:sub>750</jats:sub>, Mw = 750 g mol<jats:sup>−1</jats:sup>) in the PVDF‐HFP matrix with an ease solvent‐casting procedure. It shows ionic conductivity of 0.1 mS cm<jats:sup>−1</jats:sup> at 25 °C, more than 250 h resistance to stripping/plating, and impressive results during cycling tests in LMB with LiFePO<jats:sub>4</jats:sub> cathode.</jats:p>