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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ruffo, Riccardo
University of Milano-Bicocca
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Host–Guest Interactions and Transport Mechanism in Poly(vinylidene fluoride)-Based Quasi-Solid Electrolytes for Lithium Metal Batteriescitations
- 2024PVDF‐HFP Based, Quasi‐Solid Nanocomposite Electrolytes for Lithium Metal Batteriescitations
- 2023Highly Reversible Ti/Sn Oxide Nanocomposite Electrodes for Lithium Ion Batteries Obtained by Oxidation of Ti<sub>3</sub>Al<sub>(1‐x)</sub>Sn<sub>x</sub>C<sub>2</sub> Phasescitations
- 2023Unraveling the Electrochemical Mechanism in Tin Oxide/MXene Nanocomposites as Highly Reversible Negative Electrodes for Lithium‐Ion Batteriescitations
- 2022Unveiling the Role of PEO-Capped TiO2 Nanofiller in Stabilizing the Anode Interface in Lithium Metal Batteriescitations
- 2022Design of high-performance antimony/MXene hybrid electrodes for sodium-ion batteriescitations
- 2020Polymer-in-Ceramic Nanocomposite Solid Electrolyte for Lithium Metal Batteries Encompassing PEO-Grafted TiO<sub>2</sub> Nanocrystalscitations
- 2020Polymer-in-Ceramic Nanocomposite Solid Electrolyte for Lithium Metal Batteries Encompassing PEO-Grafted TiO2 Nanocrystalscitations
- 2019Transition metal oxides on reduced graphene oxide nanocomposites: Evaluation of physicochemical propertiescitations
- 2018Synthesis and characterization of Fe2O3/reduced graphene oxide nanocomposite as a high-performance anode material for sodium-ion batteries
- 2016Multichromophoric Electrochromic Polymers toward High Contrast Neutral Tint See-Through Electrochromic Devices
- 2015Influence of doping elements on the formation rate of silicon nanowires by silver-assisted chemical etchingcitations
- 2014Neutron Diffraction and Electrochemical Study of FeNb11O29/Li11FeNb11O29for Lithium Battery Anode Applicationscitations
- 2014Post-deposition Activation of Latent Hydrogen-Bonding: A New Paradigm for Enhancing the Performances of Bulk Heterojunction Solar Cellscitations
- 2011Macroporous WO3 thin films active in NH3 sensing: role of the hosted Cr isolated centers and Pt nanoclusterscitations
- 2010One-Step Preparation of SnO2 and Pt-Doped SnO2 As Inverse Opal Thin Films for Gas Sensingcitations
- 2006Electrical behaviour of LSGM-LSM composite cathode materialscitations
- 2005The system A12O3 and (Sr,Mg)-doped LaGaO3: Phase composition and electrical propertiescitations
- 2003Nanocrystalline SnO2-Based Thin Films Obtained by Sol−Gel Route: A Morphological and Structural Investigationcitations
- 2003Nanocrystalline SnO2-Based Thin Films Obtained by Sol-Gel Route: A Morphological and Structural Investigationcitations
Places of action
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article
PVDF‐HFP Based, Quasi‐Solid Nanocomposite Electrolytes for Lithium Metal Batteries
Abstract
<jats:title>Abstract</jats:title><jats:p>Composite polymer electrolytes are systems of choice for future solid‐state lithium metal batteries (LMBs). Poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP) is among the most interesting matrices to develop new generation quasi‐solid electrolytes (QSEs). Here it is reported on nanocomposites made of PVDF‐HFP and pegylated SiO<jats:sub>2</jats:sub> nanoparticles. Silica‐based hybrid nanofillers are obtained by grafting chains of poly(ethylene glycol) methyl ether (PEG) with different molecular weight on the surface of silica nanoparticles. The functionalized nanofiller improves the mechanical, transport and electrochemical properties of the QSEs, which show good ionic conductivity values and high resistance against dendrite penetration, ensuring boosted long and safe device operation. The most promising result is obtained by dispersing 5 wt% of SiO<jats:sub>2</jats:sub> functionalized with short PEG chains (PEG<jats:sub>750</jats:sub>, Mw = 750 g mol<jats:sup>−1</jats:sup>) in the PVDF‐HFP matrix with an ease solvent‐casting procedure. It shows ionic conductivity of 0.1 mS cm<jats:sup>−1</jats:sup> at 25 °C, more than 250 h resistance to stripping/plating, and impressive results during cycling tests in LMB with LiFePO<jats:sub>4</jats:sub> cathode.</jats:p>