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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Campoy-Quiles, Mariano
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024High Polymer Molecular Weight Yields Solar Cells with Simultaneously Improved Performance and Thermal Stabilitycitations
- 2024High Polymer Molecular Weight Yields Solar Cells with Simultaneously Improved Performance and Thermal Stabilitycitations
- 2024Using spatial confinement to decipher polymorphism in the organic semiconductor p-DTS(FBTTh2)2citations
- 2024Electrically Programmed Doping Gradients Optimize the Thermoelectric Power Factor of a Conjugated Polymercitations
- 2024A Universal, Highly Stable Dopant System for Organic Semiconductors Based on Lewis-Paired Dopant Complexes
- 2024Impact of Oligoether Side-Chain Length on the Thermoelectric Properties of a Polar Polythiophenecitations
- 2023Laminated Organic Photovoltaic Modules for Agrivoltaics and Beyond: An Outdoor Stability Study of All-Polymer and Polymer:Small Molecule Blendscitations
- 2023In-plane thermal diffusivity determination using beam-offset frequency-domain thermoreflectance with a one-dimensional optical heat sourcecitations
- 2022Unraveling the Influence of the Preexisting Molecular Order on the Crystallization of Semiconducting Semicrystalline Poly(9,9-di‑n‑octylfluorenyl-2,7-diyl (PFO)citations
- 2022Comparing the microstructure and photovoltaic performance of 3 perylene imide acceptors with similar energy levels but different packing tendenciescitations
- 2022Comparing the Microstructure and Photovoltaic Performance of 3 Perylene Imide Acceptors With Similar Energy Levels but Different Packing Tendenciescitations
- 2020Microfluidic-Assisted Blade Coating of Compositional Libraries for Combinatorial Applications: The Case of Organic Photovoltaicscitations
- 2020Reply to the “Comment on the publication ‘Ferroelectricity-free lead halide perovskites’ by Gomez ” by Colsmanncitations
- 2019Solar Harvesting: a Unique Opportunity for Organic Thermoelectrics?citations
- 2018Pressure-Induced Locking of Methylammonium Cations versus Amorphization in Hybrid Lead Iodide Perovskitescitations
- 2017A Solution-Doped Polymer Semiconductor : Insulator Blend for Thermoelectricscitations
- 2016A Solution-Doped Polymer Semiconductor:Insulator Blend for Thermoelectricscitations
- 2015Vertical and lateral morphology effects on solar cell performance for a thiophene-quinoxaline copolymer : PC_{70}BM blendcitations
- 2015Reversible Hydration of CH3NH3Pbl3 in Films, Single Crystals, and Solar Cellscitations
- 2015Reversible hydration of CH3NH3PbI3 in films, single crystals, and solar cellscitations
Places of action
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article
High Polymer Molecular Weight Yields Solar Cells with Simultaneously Improved Performance and Thermal Stability
Abstract
<jats:title>Abstract</jats:title><jats:p>Simple synthetic routes, high active layer thickness tolerance as well as stable organic solar cells are relentlessly pursued as key enabling traits for the upscaling of organic photovoltaics. Here, the potential to address these issues by tuning donor polymer molecular weight is investigated. Specifically, the focus is on PTQ10, a polymer with low synthetic complexity, with number average molecular weights of 2.4, 6.2, 16.8, 52.9, and 54.4 kDa, in combination with three different non‐fullerene acceptors, namely Y6, Y12, and IDIC. Molecular weight, indeed, unlocks a threefold increase in power conversion efficiency for these blends. Importantly, efficiencies above 10% for blade coated devices with thicknesses between 200 and 350 nm for blends incorporating high molecular weight donor are shown. Spectroscopic, GIWAXS and charge carrier mobility data suggest that the strong photocurrent improvement with molecular weight is related to both, improved electronic transport and polymer contribution to exciton generation. Moreover, it is demonstrated that solar cells based on high molecular weight PTQ10 are more thermally stable due to a higher glass transition temperature, thus also improving device stability.</jats:p>