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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lebedev, Oleg
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Entanglement of cation ordering and manipulation of the magnetic properties through a temperature-controlled topotactic interface reaction in nanocomposite perovskite oxides
- 2024PbSe Quantum Dot Superlattice Thin Films for Thermoelectric Applicationscitations
- 2024Structural, optical, and electronic properties of single crystals of 4H lead-based hexagonal hybrid perovskite
- 2023Artificial Aging of Thin Films of the Indium-Free Transparent Conducting Oxide SrVO 3citations
- 2022Mixed (Sr 1 − x Ca x ) 33 Bi 24 Al 48 O 141 fullerenoids: the defect structure analysed by (S)TEM techniques
- 20225D total scattering computed tomography reveals the full reaction mechanism of a bismuth vanadate lithium ion battery anodecitations
- 20223D LiMn 2 O 4 Thin Film Deposited by ALD: A Road toward High‐Capacity Electrode for 3D Li‐Ion Microbatteriescitations
- 20223D LiMn<sub>2</sub>O<sub>4</sub> Thin Film Deposited by ALD: A Road toward High‐Capacity Electrode for 3D Li‐Ion Microbatteriescitations
- 2022Synthetic strategy for metallophthalocyanine covalent organic frameworks for electrochemical water oxidationcitations
- 2022Path Less Traveled: A Contemporary Twist on Synthesis and Traditional Structure Solution of Metastable LiNi 12 B 8citations
- 2021Transport and Thermoelectric Coefficients of the Co 9 S 8 Metal: A Comparison with the Spin Polarized CoS 2citations
- 2020Lithium-driven conversion and alloying mechanisms in core-shell Sn/SnOx nanoparticlescitations
- 2020A scalable synthesis route for multiscale defect engineering in the sustainable thermoelectric quaternary sulfide Cu26V2Sn6S32citations
- 2020Li 2 O:Li–Mn–O Disordered Rock‐Salt Nanocomposites as Cathode Prelithiation Additives for High‐Energy Density Li‐Ion Batteriescitations
- 2019Sn(TFSI) 2 as Suitable Salt For the Electrodeposition of Nanostructured Cu 6 Sn 5 - Sn Composite obtained on Cu electrode in Ionic Liquidcitations
- 2017Layered tellurides: stacking faults induce low thermal conductivity in the new In 2 Ge 2 Te 6 and thermoelectric properties of related compoundscitations
- 2014Structural, magnetic and transport properties of 2D structured perovskite oxychalcogenidescitations
- 2014ZrSe 3 -Type Variant of TiS 3 : Structure and Thermoelectric Propertiescitations
- 2014Influence of the structure on the properties of <tex>$Na_{x}Eu_{y}(MoO_{4})_{z}$</tex> red phosphorscitations
- 2012Magnetodielectric CuCr 0.5 V 0.5 O 2 : an example of a magnetic and dielectric multiglasscitations
- 2007Critical temperature modification of low dimensional superconductors by spin dopingcitations
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article
3D LiMn<sub>2</sub>O<sub>4</sub> Thin Film Deposited by ALD: A Road toward High‐Capacity Electrode for 3D Li‐Ion Microbatteries
Abstract
Miniaturized electronics suffer from a lack of energy autonomy. In that context, the fabrication of lithium-ion solid-state microbatteries with high performance is mandatory for powering the next generation of portable electronic devices. Here, the fabrication of a thin film positive electrode for 3D Li-ion microbatteries made by the atomic layer deposition (ALD) method and in situ lithiation step is demonstrated. The 3D electrodes based on spinel LiMn2 O4 films operate at high working potential (4.1 V vs Li/Li+ ) and are capable of delivering a remarkable surface capacity (≈180 μAh cm-2 ) at low C-rate while maintaining more than 40 μAh cm-2 at C/2 (time constant = 2 h). Both the thickness of the electrode material and the 3D gain of the template are carefully tuned to maximize the electrode performance. Advanced characterization techniques such as transmission electron and X-ray transmission microscopies are proposed as perfect tools to study the conformality of the deposited films and the interfaces between each layer: no interdiffusion or segregation are observed. This work represents a major issue towards the fabrication of 3D-lithiated electrode by ALD-without any prelithiation step by electrochemical technique-making it an attractive solution for the fabrication of 3D Li-ion solid-state microbatteries with semiconductor processing methods.