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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rensmo, Håkan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Composition dependence of X-ray stability and degradation mechanisms at lead halide perovskite single crystal surfacescitations
- 2024Electronic structure characterization by photoelectron spectroscopy of BaZrS3 perovskite powder and thin filmcitations
- 2023Direct measurements of interfacial photovoltage and band alignment in perovskite solar cells using hard X-ray photoelectron spectroscopycitations
- 2023Interplay between Growth Mechanism, Materials Chemistry, and Band Gap Characteristics in Sputtered Thin Films of Chalcogenide Perovskite BaZrS3citations
- 2022Experimental and Theoretical Core Level and Valence Band Analysis of Clean Perovskite Single Crystal Surfacescitations
- 2022Experimental and Theoretical Core Level and Valence Band Analysis of Clean Perovskite Single Crystal Surfacescitations
- 2022Atomic Layer Grown Zinc–Tin Oxide as an Alternative Buffer Layer for Cu2ZnSnS4-Based Thin Film Solar Cells: Influence of Absorber Surface Treatment on Buffer Layer Growthcitations
- 2022Surface/Interface Effects by Alkali Postdeposition Treatments of (Ag,Cu)(In,Ga)Se2 Thin Film Solar Cellscitations
- 2022Atomic Layer Grown Zinc-Tin Oxide as an Alternative Buffer Layer for Cu2ZnSnS4-Based Thin Film Solar Cells : Influence of Absorber Surface Treatment on Buffer Layer Growthcitations
- 2021Nonlocal Interactions in the Double Perovskite Sr2FeMoO6 from Core-Level X‐ray Spectroscopycitations
- 2020Simple Method for Efficient Slot-Die Coating of MAPbI(3) Perovskite Thin Films in Ambient Air Conditionscitations
- 2020Tuning the Bandgap in Silver Bismuth Iodide Materials by Partly Substituting Bismuth with Antimony for Improved Solar Cell Performancecitations
- 2020Origin of itinerant carriers in antiferromagnetic LaFe1-xMoxO3 studied by x-ray spectroscopiescitations
- 2018Maximizing and stabilizing luminescence from halide perovskites with potassium passivationcitations
- 2018Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
- 2018Potassium- and Rubidium-Passivated Alloyed Perovskite Films: Optoelectronic Properties and Moisture Stability.
- 2018Dedoping of Lead Halide Perovskites Incorporating Monovalent Cations.
- 2017Partially Reversible Photoinduced Chemical Changes in a Mixed-Ion Perovskite Material for Solar Cellscitations
- 2015Chemical engineering of methylammonium lead iodide/bromide perovskites : tuning of opto-electronic properties and photovoltaic performancecitations
- 2012Nanosilicon electrodes for lithium-ion batteries: Interfacial mechanisms studied by hard and soft X-ray photoelectron spectroscopycitations
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article
Experimental and Theoretical Core Level and Valence Band Analysis of Clean Perovskite Single Crystal Surfaces
Abstract
<jats:title>Abstract</jats:title><jats:p>A detailed understanding of the surface and interface properties of lead halide perovskites is of interest for several applications, in which these materials may be used. To develop this understanding, the study of clean crystalline surfaces can be an important stepping stone. In this work, the surface properties and electronic structure of two different perovskite single crystal compositions (MAPbI<jats:sub>3</jats:sub> and Cs<jats:italic><jats:sub>x</jats:sub></jats:italic>FA<jats:sub>1–</jats:sub><jats:italic><jats:sub>x</jats:sub></jats:italic>PbI<jats:sub>3</jats:sub>) are investigated using synchrotron‐based soft X‐ray photoelectron spectroscopy (PES), molecular dynamics simulations, and density functional theory. The use of synchrotron‐based soft X‐ray PES enables high surface sensitivity and nondestructive depth‐profiling. Core level and valence band spectra of the single crystals are presented. The authors find two carbon 1s contributions at the surface of MAPbI<jats:sub>3</jats:sub> and assign these to MA<jats:sup>+</jats:sup> ions in an MAI‐terminated surface and to MA<jats:sup>+</jats:sup> ions below the surface. It is estimated that the surface is predominantly MAI‐terminated but up to 30% of the surface can be PbI<jats:sub>2</jats:sub>‐terminated. The results presented here can serve as reference spectra for photoelectron spectroscopy investigations of technologically relevant polycrystalline thin films, and the findings can be utilized to further optimize the design of device interfaces.</jats:p>