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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Meille, Sylvain
Institut National des Sciences Appliquées de Lyon
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (44/44 displayed)
- 2024Explanation of edge defect influence on sapphire bending strength scatter using the coupled criterioncitations
- 20233D printed triply periodic minimal surfaces calcium phosphate bone substitute: The effect of porosity design on mechanical propertiescitations
- 2023Anisotropic fracture in nacre-like aluminacitations
- 20233D-printing of ceramic filaments with ductile metallic corescitations
- 2022Anisotropic fracture in nacre-like aluminacitations
- 2022Nacre-like alumina composites reinforced by zirconia particlescitations
- 2022Toughening mechanisms in nacre-like alumina revealed by in-situ imaging of stresscitations
- 2022Ultrafast Remote Healing of Magneto-Responsive Thermoplastic Elastomer-Based Nanocompositescitations
- 2022Prediction of crack nucleation and propagation in porous ceramics using the phase-field approachcitations
- 2021Mechanical properties of unidirectional, porous polymer/ceramic composites for biomedical applicationscitations
- 2021Fracture of Porous Ceramics: Application to the Mechanical Degradation of Solid Oxide Cell During Redox Cyclingcitations
- 2021Robocasting of highly porous ceramics scaffolds with hierarchized porositycitations
- 20213D Printing and Pyrolysis of Optical ZrO 2 Nanostructures by Two‐Photon Lithography: Reduced Shrinkage and Crystallization Mediated by Nanoparticles Seedscitations
- 20213D printing and pyrolysis of optical ZrO$_2$ nNanostructures by two-photon lithography: reduced shrinkage and crystallization mediated by nanoparticles seedscitations
- 2020Mechanical characterization of meso-porous alumina by micro- and nano-indentationcitations
- 2020Nacre-like alumina composites based on heteroaggregationcitations
- 2020Highlighting the role of heterogeneity on the indentation hardness of foamed gypsumcitations
- 2020A simple approach to bulk bioinspired tough ceramicscitations
- 2020Determination of interface fracture properties by micro-and macro-scale experiments in nacre-like aluminacitations
- 2020Interface failure in nacre-like aluminacitations
- 2019Novel calcium phosphate/PCL graded samples: Design and development in view of biomedical applicationscitations
- 2018Bouncing and 3D printable hybrids with self-healing propertiescitations
- 2018Strong and tough metal/ceramic micro‐laminatescitations
- 2018Reply to the correspondence:" On the fracture toughness of bioinspired ceramic materials"
- 2017Modeling and in‐situ evaluation of thermal gradients during sintering of large ceramic ballscitations
- 2017Using graphene networks to build bioinspired self-monitoring ceramicscitations
- 2017Strain rate influence on human cortical bone toughness: A comparative study of four paired anatomical sitescitations
- 2017Fracture behavior of robocast HA/beta-TCP scaffolds studied by X-ray tomography and finite element modelingcitations
- 2016Identification of a damage criterion of a highly porous alumina ceramiccitations
- 2016Towards high temperature electronic modules in which all components would be attached using silver sintering
- 2016Selective etching of injection molded zirconia-toughened alumina: towards osseointegrated and antibacterial ceramic implantscitations
- 2016Mechanical behaviour of a beta-TCP ceramic with a random porosity: Study of the fracture path with X-ray tomographycitations
- 2016CoCrMo cellular structures made by Electron Beam Melting studied by local tomography and finite element modellingcitations
- 2014Strong, tough and stiff bioinspired ceramics from brittle constituentscitations
- 2014Strong, tough and stiff bioinspired ceramics from brittle constituentscitations
- 2013Organic-inorganic composites for bone substitute and bone repair applications: concepts, first results and potentialities
- 2012Degradation of Bioceramics.citations
- 2012Mechanical properties of porous ceramics in compression: On the transition between elastic, brittle, and cellular behaviorcitations
- 2012Bioactivity modulation of Bioglass ® powder by thermal treatmentcitations
- 2011Identification de comportements à la rupture, de mécanismes d'endommagement et de dissipations d'énergie à partir de méthodes de corrélation d'images
- 2010Damage law identification of a quasi brittle ceramic from a bending test using digital image correlationcitations
- 2003Mechanisms of crack propagation in dry plaster
- 2001Relation between microstructure and mechanical properties of set plaster
- 2001Linear elastic properties of 2D and 3D models of porous materials made from elongated objects
Places of action
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article
3D printing and pyrolysis of optical ZrO$_2$ nNanostructures by two-photon lithography: reduced shrinkage and crystallization mediated by nanoparticles seeds
Abstract
Two-photon lithography is a potential route to produce high-resolution 3D ceramics. However, the large shrinkage due to the elimination of an impor-tant organic counterpart of the printed material during debinding/sintering remains a lock to further development of this technology. To limit this phenomenon, an original approach based on a composite resin incorporating 45 wt% ultrasmall (5 nm) zirconia stabilized nanoparticles into the zirconium acrylate precursor is proposed to process 3D zirconia microlattices and nano-structured optical surfaces. Interestingly, the nanoparticles are used both as seeds allowing control of the crystallographic phase formed during the calcination process and as structural stabilizing agent preventing important shrinkage of the printed ceramic. After 3D photolithography and pyrolysis, the weight and volume loss of the microstructures are drastically reduced as compared to similar systems processed with the reference resin without nanoparticles, and stable 3D microstructures of cubic zirconia are obtained with high spatial resolution. In the case of a patterned surface, the refractive index of 2.1 leads to a diffraction efficiency large enough to obtain microfo-cusing with linewidths of 0.1 μm, and the demonstration of a microlens array with a period as small as 0.8 μm