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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Müller, Ralph
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024GaAs//CuInGaSe-Based Multijunction Solar Cells with 30% Efficiency Under Low Concentrated Sunlight
- 2022Long-term mechanical loading is required for the formation of 3D bioprinted functional osteocyte bone organoidscitations
- 2022Integrated Solar-Driven Device with a Front Surface Semitransparent Catalysts for Unassisted CO2 Reductioncitations
- 2021Nano‐3D‐printed photochromic micro‐objectscitations
- 2020Silicon-Based Monolithic Triple-Junction Solar Cells with Conversion Efficiency >34%
- 2018An automated step-wise micro-compression device for 3D dynamic image-guided failure assessment of bone tissue on a microstructural level using time-lapsed tomographycitations
- 2017On the determination of the contact resistivity for passivating contacts using 3D simulations
- 2015Effect of fetal bovine serum on mineralization in silk fibroin scaffoldscitations
- 2015Ion-implanted laser-annealed p+ and n+ regions. A potential solution for industrially feasible high-efficiency n-type interdigitated back-contact solar cellscitations
- 2013A quantitative framework for the 3D characterization of the osteocyte lacunar systemcitations
- 2011Analysis of sintered polymer scaffolds using concomitant synchrotron computed tomography and in situ mechanical testingcitations
- 2003Tomography studies of human foreskin fibroblasts on polymer yarnscitations
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article
Nano‐3D‐printed photochromic micro‐objects
Abstract
Molecular photoswitches that can reversibly change color upon irradiation are promising materials for applications in molecular actuation and photoresponsive materials. However, the fabrication of photochromic devices is limited to conventional approaches such as mold casting and spin-coating, which cannot fabricate complex structures. Reported here is the first photoresist for direct laser writing of photochromic 3D micro-objects via two-photon polymerization. The integration of photochromism into thiol-ene photo-clickable resins enables rapid two-photon laser processing of highly complex microstructures and facile postmodification using a series of donor-acceptor Stenhouse adduct (DASA) photoswitches with different excitation wavelengths. The versatility of thiol–ene photo-click reactions allows fine-tuning of the network structure and physical properties as well as the type and concentration of DASA. When exposed to visible light, these microstructures exhibit excellent photoresponsiveness and undergo reversible color-changing via photoisomerization. It is demonstrated that the fluorescence variations of DASAs can be used as a reporter of photoswitching and thermal recovery, allowing the reading of DASA-containing sub-micrometric structures in 3D. This work delivers a new approach for custom microfabrication of 3D photochromic objects with molecularly engineered color and responsiveness.