| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Cherevko, Serhiy
Forschungszentrum Jülich
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Operando Fe dissolution in Fe–N–C electrocatalysts during acidic oxygen reduction: Impact of local pH changecitations
- 2023Isopropanol electro-oxidation on Pt-Ru-Ircitations
- 2022Graphene-derived carbon support boosts proton exchange membrane fuel cell catalyst stabilitycitations
- 2022Atomistic Insights into Activation and Degradation of La0.6Sr0.4CoO3-δElectrocatalysts under Oxygen Evolution Conditionscitations
- 2022Catalyst Dissolution Analysis in PEM Water Electrolyzers during Intermittent Operationcitations
- 2022Hydrogen evolution in alkaline medium on intratube and surface decorated PtRu catalystcitations
- 2022Atomistic Insights into Activation and Degradation of La0.6Sr0.4CoO3−δ Electrocatalysts under Oxygen Evolution Conditionscitations
- 2022High-throughput exploration of activity and stability for identifying photoelectrochemical water splitting materialscitations
- 2021Electrocatalytic oxidation of 2-propanol on PtxIr100-x bifunctional electrocatalysts - aA thin-film materials library studycitations
- 2020Evolution of the PtNi Bimetallic Alloy Fuel Cell Catalyst under Simulated Operational Conditionscitations
- 2020Insight into the Mechanisms of High Activity and Stability of Iridium Supported on Antimony-Doped Tin Oxide Aerogel for Anodes of Proton Exchange Membrane Water Electrolyzerscitations
- 2020Fabrication of a Robust PEM Water Electrolyzer Based on Non‐Noble Metal Cathode Catalyst: [Mo<sub>3</sub>S<sub>13</sub>]<sup>2−</sup> Clusters Anchored to N‐Doped Carbon Nanotubescitations
- 2020The Dissolution Dilemma for Low Pt Loading Polymer Electrolyte Membrane Fuel Cell Catalystscitations
- 2020Fabrication of a Robust PEM Water Electrolyzer Based on Non‐Noble Metal Cathode Catalyst: [Mo3S13]2− Clusters Anchored to N‐Doped Carbon Nanotubes
- 2020Improved Hydrogen Oxidation Reaction Activity and Stability of Buried Metal-Oxide Electrocatalyst Interfacescitations
- 2020Improved Hydrogen Oxidation Reaction Activity and Stability of Buried Metal-Oxide Electrocatalyst Interfacescitations
- 2018Using Instability of a Non-stoichiometric Mixed Oxide Oxygen Evolution Catalyst As a Tool to Improve Its Electrocatalytic Performancecitations
- 2018The stability number as a metric for electrocatalyst stability benchmarkingcitations
- 2017Electrocatalytic synthesis of hydrogen peroxide on Au-Pd nanoparticles: from fundamentals to continuous productioncitations
- 2016Activity and stability of electrochemically and thermally treated iridium for the oxygen evolution reactioncitations
- 2016Oxygen and hydrogen evolution reactions on Ru, RuO2, Ir, and IrO2 thin film electrodes in acidic and alkaline electrolytes: A comparative study on activity and stabilitycitations
- 2014Hierarchical nanoporous films obtained by surface cracking on Cu-Au and ethanethiol on Au(001)citations
Places of action
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article
Fabrication of a Robust PEM Water Electrolyzer Based on Non‐Noble Metal Cathode Catalyst: [Mo<sub>3</sub>S<sub>13</sub>]<sup>2−</sup> Clusters Anchored to N‐Doped Carbon Nanotubes
Abstract
<jats:title>Abstract</jats:title><jats:p>High investment costs and a dependence on noble metal catalysts currently obstruct the large‐scale implementation of proton exchange membrane water electrolyzers (PEMWEs) for converting fluctuating green electricity into chemical energy via water splitting. In this context, this work presents a high‐performing and stable non‐noble metal catalyst for the hydrogen evolution reaction (HER), consisting of [Mo<jats:sub>3</jats:sub>S<jats:sub>13</jats:sub>]<jats:sup>2−</jats:sup> clusters supported on nitrogen doped carbon nanotubes (NCNTs). Strikingly, a significant electrochemically induced activation of the Mo<jats:sub>3</jats:sub>S<jats:sub>13</jats:sub>‐NCNT catalyst at high current densities is observed in full cell configuration, enabling a remarkable current density of 4 A cm<jats:sup>−2</jats:sup> at a cell voltage of 2.36 V. To the authors’ knowledge, this is the highest reported value to date for a PEMWE full cell using a non‐noble metal HER catalyst. Furthermore, only a minor degradation of 83 µV h<jats:sup>−1</jats:sup> is observed during a stability test of 100 h constant current at 1 A cm<jats:sup>−2</jats:sup>, with a nearly unchanged polarization behavior after the current hold. Catalyst stability and activity are additionally analyzed via online dissolution measurements. X‐ray photoelectron spectroscopy examination of the catalyst before and after electrochemical application reveals a correlation between the electrochemical activation occurring via electrodissolution with changes in the molecular structure of the Mo<jats:sub>3</jats:sub>S<jats:sub>13</jats:sub>‐NCNT catalyst.</jats:p>