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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Guerrero, Antonio
Universitat Jaume I
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (34/34 displayed)
- 2024Electrodeposited NiO anode interlayers: Enhancement of the charge carrier selectivity inorganic solar cells.citations
- 2023Nanocomposition of PEDOT:PSS with metal phthalocyanines as promising hole transport layers for organic photovoltaicscitations
- 2023Biocomposites from porcine plasma protein and urban parks and gardens green wastecitations
- 2023Impact of Scan Rate and Mobile Ion Concentration on the Anomalous J-V Curves of Metal Halide Perovskite-Based Memristors
- 2023Role of Metal Contacts on Halide Perovskite Memristorscitations
- 2023Role of Metal Contacts on Halide Perovskite Memristorscitations
- 2022High-sensitivity high-resolution X-ray imaging with soft-sintered metal halide perovskitescitations
- 2022Impedance Spectroscopy of Metal Halide Perovskite Solar Cells from the Perspective of Equivalent Circuitscitations
- 2022Highly porous Ti–Ni anodes for electrochemical oxidationscitations
- 2022Transition from Capacitive to Inductive Hysteresis: A Neuron-Style Model to Correlate I–V Curves to Impedances of Metal Halide Perovskitescitations
- 2022Assessing the drawbacks and benefits of ion migration in lead halide perovskitescitations
- 2022High-Efficiency Digital Inkjet-Printed Non-Fullerene Polymer Blends Using Non-Halogenated Solventscitations
- 2021Mobile Ion-Driven Modulation of Electronic Conductivity Explains Long-Timescale Electrical Response in Lead Iodide Perovskite Thick Pelletscitations
- 2021Spectral properties of the dynamic state transition in metal halide perovskite-based memristor exhibiting negative capacitancecitations
- 2021High-sensitivity high-resolution X-ray imaging with soft-sintered metal halide perovskitescitations
- 2019Impedance spectroscopy of perovskite/contact interface: Beneficial chemical reactivity effectcitations
- 2019Ionic Effect Enhances Light Emission and the Photovoltage of Methylammonium Lead Bromide Perovskite Solar Cells by Reduced Surface Recombinationcitations
- 2019Semiconductor α‐Fe2O3 Hematite Fabricated Electrode for Sensitive Detection of Phenolic Pollutantscitations
- 2019Reversible Formation of Gold Halides in Single‐Crystal Hybrid‐Perovskite/Au Interface upon Biasing and Effect on Electronic Carrier Injectioncitations
- 2019Quantification of Ionic Diffusion in Lead Halide Perovskite Single Crystalscitations
- 2019Unravelling the role of vacancies in lead halide perovskite through electrical switching of photoluminescencecitations
- 2019Perovskite solar cells with versatile electropolymerized fullerene as electron extraction layercitations
- 2018Real-Time Observation of Iodide Ion Migration in Methylammonium Lead Halide Perovskitescitations
- 2018Quantification of Ionic Diffusion in Lead Halide Perovskite Single Crystalscitations
- 2017Real-Time Observation of Iodide Ion Migration in Methylammonium Lead Halide Perovskitescitations
- 2017Toward High-Temperature Stability of PTB7-Based Bulk Heterojunction Solar Cells: Impact of Fullerene Size and Solvent Additivecitations
- 2017Toward High-Temperature Stability of PTB7-Based Bulk Heterojunction Solar Cells: Impact of Fullerene Size and Solvent Additivecitations
- 2017Recent advances to understand morphology stability of organic photovoltaicscitations
- 2016Ligand-Free Synthesis of Aluminum-Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color-Tuned Highly Efficient Organic Solar Cellscitations
- 2016Ligand-Free Synthesis of Aluminum-Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color-Tuned Highly Efficient Organic Solar Cellscitations
- 2016Ligand-free synthesis of aluminum-doped zinc oxide nanocrystals and their use as optical spacers in color-tuned highly efficient organic solar cellscitations
- 2016Predicting thermal stability of organic solar cells through an easy and fast capacitance measurementcitations
- 2015Germanium coating boosts lithium uptake in Si nanotube battery anodescitations
- 2014Electrodeposited NiO anode interlayers: Enhancement of the charge carrier selectivity in organic solar cellscitations
Places of action
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article
Real-Time Observation of Iodide Ion Migration in Methylammonium Lead Halide Perovskites
Abstract
<p>Organic-inorganic metal halide perovskites (e.g., CH3NH3PbI3-xClx) emerge as a promising optoelectronic material. However, the Shockley-Queisser limit for the power conversion efficiency (PCE) of perovskite-based photovoltaic devices is still not reached. Nonradiative recombination pathways may play a significant role and appear as photoluminescence (PL) inactive (or dark) areas on perovskite films. Although these observations are related to the presence of ions/defects, the underlying fundamental physics and detailed microscopic processes, concerning trap/defect status, ion migration, etc., still remain poorly understood. Here correlated wide-field PL microscopy and impedance spectroscopy are utilized on perovskite films to in situ investigate both the spatial and the temporal evolution of these PL inactive areas under external electric fields. The formation of PL inactive domains is attributed to the migration and accumulation of iodide ions under external fields. Hence, we are able to characterize the kinetic processes and determine the drift velocities of these ions. In addition, it is shown that I-2 vapor directly affects the PL quenching of a perovskite film, which provides evidence that the migration/segregation of iodide ions plays an important role in the PL quenching and consequently limits the PCE of organometal halide-based perovskite photovoltaic devices.</p>