| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gogoi, Nayanmoni
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Topics
Publications (2/2 displayed)
- 2022Influence of the Capping Ligands on the Self‐Assembly of Cyanido‐Bridged Mn(II)‐Fe(III) Aggregates: Synthesis, Crystal Structures, Electrochemical and Magnetic Propertiescitations
- 2010A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2] . 3CH3CN assembled from 2-hydroxyethyl-3,5-dimethyl pyrazolecitations
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article
Influence of the Capping Ligands on the Self‐Assembly of Cyanido‐Bridged Mn(II)‐Fe(III) Aggregates: Synthesis, Crystal Structures, Electrochemical and Magnetic Properties
Abstract
<jats:title>Abstract</jats:title><jats:p>Reaction of Mn(II) salts with a meridional tricyanido iron(III) linker, [Fe(bbp)(CN)<jats:sub>3</jats:sub>]<jats:sup>2−</jats:sup> (H<jats:sub>2</jats:sub>bbp=bis(2‐benzimidazolyl)pyridine) was investigated in presence of two different N‐donor blocking ligands. Two heterometallic Mn(II)/Fe(III) aggregates <jats:italic>viz</jats:italic>. [Mn(cptp)<jats:sub>2</jats:sub>][Fe(bbp)(CN)<jats:sub>3</jats:sub>] ⋅ 3H<jats:sub>2</jats:sub>O (<jats:bold>1</jats:bold>) (cptp=4’‐(4‐chlorophenyl)‐2,2’ : 6’,2’’‐terpyridine) and [Mn(CH<jats:sub>3</jats:sub>OH)<jats:sub>2</jats:sub>(μ‐NC)<jats:sub>3</jats:sub>Fe(bbp)]<jats:sub><jats:italic>n</jats:italic></jats:sub> (<jats:bold>2</jats:bold>) are isolated and characterized by using analytical, spectroscopic, structural, electrochemical and magnetic investigations. Single crystal X‐ray diffraction analysis show that compound <jats:bold>1</jats:bold> is a heterobimetallic complex salt, while compound <jats:bold>2</jats:bold> is a cyanido bridged Mn(II)−Fe(III) ladder shaped chain. The electrochemical behaviours of both compounds <jats:bold>1</jats:bold> and <jats:bold>2</jats:bold> exhibit multiple redox accessible states associated with the corresponding metal centres. Investigation of magnetic properties of <jats:bold>2</jats:bold> manifest interplay of antiferromagnetic interaction between low‐spin Fe(III) and high‐spin Mn(II) ions.</jats:p>