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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sheykhabadi, Parvan Ghaderi
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article
A Novel Recyclable Ni/Cu/Fe Termetallic Nanocatalyst for the Synthesis of Propargylamines through the A<sup>3</sup>‐Coupling Reactions
Abstract
<jats:title>Abstract</jats:title><jats:p>A novel Ni/Cu/Fe nanocatalyst was prepared <jats:italic>via</jats:italic> a three‐step procedure for the A<jats:sup>3</jats:sup>‐coupling reaction of an aldehyde, an amine, and a terminal alkyne to synthesize the corresponding propargylamine. Oleic acid was used in the second step to avoid aggregation of CuFe<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub> nanoparticles. The prepared <jats:bold>NiO/OA‐CuFe<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub></jats:bold> (Ni/Cu/Fe) was characterized using X‐ray diffraction (XRD), scanning electron microscopy/wavelength dispersive X‐ray (SEM/WDX), particle size analyzer, fourier transform infrared (FT‐IR) and atomic absorption spectroscopy (AAS). A variety of propargylamines was synthesized using a very small amount of this efficient and inexpensive nanocatalyst in toluene as the solvent at 100 °C. Due to high magnetic properties of the prepared catalyst, its isolation and recycle were very easy, and it was used in five repetitive cycles.</jats:p>