| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Morsch, Suzanne
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Multi-Analytical Study of Damage to Marine Ballast Tank Coatings After Cyclic Corrosion Testing
- 2024High resolution analytical microscopy of damage progression within a polyester powder coating after cyclic corrosion testing
- 2023The effect of cross-linker structure on interfacial interactions, polymer dynamics and network composition in an epoxy-amine resincitations
- 2022The influence of mechanical grinding on the microstructure and corrosion behaviour of A356 aluminium alloyscitations
- 2022Molecular origins of Epoxy-Amine/Iron oxide interphase formationcitations
- 2021The influence of mechanical grinding on the microstructure and corrosion behaviour of A356 aluminium alloys
- 2021Local oxidation of the buried epoxy-amine/iron oxide interphasecitations
- 2021Local Oxidation of the Buried Epoxy-Amine / Iron Oxide Interphase
- 2020Spectroscopic insights into adhesion failure at the buried epoxy‐metal interphase using AFM‐IRcitations
- 2020Examining the early stages of thermal oxidative degradation in epoxy-amine resinscitations
- 2019Leaching from coatings pigmented with strontium aluminium polyphosphate inhibitor pigment- evidence for a cluster-percolation modelcitations
- 2019How pigment volume concentration (PVC) and particle connectivity affect leaching of corrosion inhibitive species from coatingscitations
- 2018The Unexpected Role of Carbonate Impurities in Polyphosphate Corrosion Inhibitioncitations
- 2017Molecularly Controlled Epoxy Network Nanostructurescitations
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article
Spectroscopic insights into adhesion failure at the buried epoxy‐metal interphase using AFM‐IR
Abstract
Local AFM‐IR analysis is performed on the organic coating residues remaining on carbon steel substrates after pull‐off adhesion tests. This approach provides unique spectral information, because scattering from these rough substrates has previously prohibited transflectance FTIR analysis of such regions. The AFM‐IR spectra of epoxy‐amine residues display characteristic oxidation bands, which can only be detected by ATR‐FTIR spectroscopy of intact coatings after thermal aging. These oxidation bands are shown to be more intense for thinner coating remnants and dominate the spectra of residue left by coatings removed after thermal aging at 70°C for 4 weeks. This, alongside distinctive changes in the macroscopic adhesion behavior after thermal aging, provides direct evidence that rapid oxidation occurs in the buried polymer‐metal interphase during thermal aging.