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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Visser, Peter
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Review of the state of art of Li-based inhibitors and coating technology for the corrosion protection of aluminium alloyscitations
- 2024Review of the state of art of Li-based inhibitors and coating technology for the corrosion protection of aluminium alloyscitations
- 2024Design, Manufacturing, and Testing of a Metallic Fuselage Panel Incorporating New Alloys and Environmentally Friendly Technologies
- 2024Spatiotemporally resolved corrosion protection of AA2024-T3 by a lithium-based conversion layercitations
- 2024Spatiotemporally resolved corrosion protection of AA2024-T3 by a lithium-based conversion layercitations
- 2023Local scanning electrochemical microscopy analysis of a lithium-based conversion layer on AA2024-T3 at progressive stages of formationcitations
- 2023Local scanning electrochemical microscopy analysis of a lithium-based conversion layer on AA2024-T3 at progressive stages of formationcitations
- 2022Chromate-Free Corrosion Protection Strategies for Magnesium Alloys—A Review: Part II—PEO and Anodizingcitations
- 2022Evaluation of the formation and protectiveness of a lithium-based conversion layer using electrochemical noisecitations
- 2022Evaluation of the formation and protectiveness of a lithium-based conversion layer using electrochemical noisecitations
- 2021Laterally-resolved formation mechanism of a lithium-based conversion layer at the matrix and intermetallic particles in aerospace aluminium alloyscitations
- 2020Chromate ion transport in epoxy films: Influence of BaSO4 particlescitations
- 2020Chromate ion transport in epoxy films: Influence of BaSO4 particlescitations
- 2019Active corrosion protection of various aluminium alloys by lithium-leaching coatingscitations
- 2018On the importance of irreversibility of corrosion inhibitors for active coating protection of AA2024-T3citations
- 2018Compositional study of a corrosion protective layer formed by leachable lithium salts in a coating defect on AA2024-T3 aluminium alloyscitations
- 2017Electrochemical evaluation of corrosion inhibiting layers formed in a defect from lithium-leaching organic coatingscitations
- 2016Lithium salts as leachable corrosion inhibitors and potential replacement for hexavalent chromium in organic coatings for the protection of aluminum alloyscitations
- 2016Study of the formation of a protective layer in a defect from lithium-leaching organic coatingscitations
- 2016An investigation of the corrosion inhibitive layers generated from lithium oxalatecontaining organic coating on AA2024-T3 aluminium alloycitations
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015Protective Film Formation on AA2024-T3 Aluminum Alloy by Leaching of Lithium Carbonate from an Organic Coating
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article
An investigation of the corrosion inhibitive layers generated from lithium oxalatecontaining organic coating on AA2024-T3 aluminium alloy
Abstract
The protective film formed in a defect by leaching of lithium oxalate from model organic coatings during neutral salt spray exposure has been investigated. A scribed area of about 1mm width was introduced on the coated AA2024-T3 aluminium alloy. The scribed area was examined before and after exposure in neutral salt spray environment for 4, 8, 24 and 168 h by scanning and transmission electron microscopies. Itwas found that the lithiumoxalatewas able to leach fromthe organic coating during neutral salt spray exposure and it promoted the formation of a film that provided effective corrosion protection to the alloy. The typical film morphology consists of three different layers, including a relatively compact layer near the alloy substrate, a porous middle layer and a columnar outer layer. Variation of the filmmorphology was also observed at different locations of the scribed alloy surface, which may be related to the difference of local concentration of lithium species. Electron energy loss spectroscopy detected<br/>lithium, aluminium and oxygen in the film. Although the film showed the varied morphologies in different regions of the scribed<br/>area, the alloy substrate was protected from corrosion when the film was formed.