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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Liu, Yanwen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Multi-Analytical Study of Damage to Marine Ballast Tank Coatings After Cyclic Corrosion Testing
- 2024High resolution analytical microscopy of damage progression within a polyester powder coating after cyclic corrosion testing
- 2021Local oxidation of the buried epoxy-amine/iron oxide interphasecitations
- 2021Local Oxidation of the Buried Epoxy-Amine / Iron Oxide Interphase
- 2020Examining the early stages of thermal oxidative degradation in epoxy-amine resinscitations
- 2019Leaching from coatings pigmented with strontium aluminium polyphosphate inhibitor pigment- evidence for a cluster-percolation modelcitations
- 2019How pigment volume concentration (PVC) and particle connectivity affect leaching of corrosion inhibitive species from coatingscitations
- 2018Multi-Modal Plasma Focused Ion Beam Serial Section Tomography of an Organic Paint Coatingcitations
- 2017Molecularly Controlled Epoxy Network Nanostructurescitations
- 2017Time-lapse lab-based X-ray nano-CT study of corrosion damagecitations
- 2017An organic coating pigmented with strontium aluminium polyphosphate for corrosion protection of zinc alloy coated steelcitations
- 2017An organic coating pigmented with strontium aluminium polyphosphate for corrosion protection of zinc alloy coated steelcitations
- 2017Influence of Volume Concentration of Active Inhibitor on Microstructure and Leaching Behaviour of a Model Primercitations
- 2016Lithium salts as leachable corrosion inhibitors and potential replacement for hexavalent chromium in organic coatings for the protection of aluminum alloyscitations
- 2016Corrosion inhibition of pure aluminium and AA2014-T6 alloy by strontium chromate at low concentrationcitations
- 2016An investigation of the corrosion inhibitive layers generated from lithium oxalatecontaining organic coating on AA2024-T3 aluminium alloycitations
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatingscitations
- 2015Protective Film Formation on AA2024-T3 Aluminum Alloy by Leaching of Lithium Carbonate from an Organic Coating
- 2010Corrosion behaviour of mechanically polished AA7075-T6 aluminium alloycitations
- 2006Morphology, composition and structure of anodic films on binary Al-Cu alloyscitations
- 2002Imaging XPS investigation of the lateral distribution of copper inclusions at the abraded surface of 2024T3 aluminium alloy and adsorption of decyl phosphonic acidcitations
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article
Imaging XPS investigation of the lateral distribution of copper inclusions at the abraded surface of 2024T3 aluminium alloy and adsorption of decyl phosphonic acid
Abstract
The XPS images of copper-rich intermetallic particles in an aluminium alloy have been obtained after argon ion removal of the oxide at the surface of mechanically polished 2024T3 alloy. Comparison of the XPS analysis before and after etching indicates that the oxide does not include significant concentrations of copper. Through analogy with copper incorporation into anodic films, it is proposed that incorporation into the oxide would only occur after preferential oxidation of aluminium and enrichment of copper immediately below the oxide film. Self-assembling monolayers of decyl phosphonic acid (DPA) have been adsorbed to the surface of 2024T3 alloy and superpure Al. The lateral distribution was mapped with XPS using the characteristic P 2s signal. The distribution of DPA was relatively uniform on both MS-Al and 2024T3. This is consistent with the model of the alloy surface constructed from the imaging XPS analysis, which suggests that the oxide on the large particles is dose in composition to that on to the surrounding matrix. Copyright © 2002 John Wiley & Sons, Ltd.