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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Biroju, Ravi Kumar
Slovak University of Technology in Bratislava
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2024Radio frequency-assisted zirconium carbide matrix deposition for continuous fiber-reinforced ultra high temperature ceramic matrix compositescitations
- 2020Spectroscopic correlation of chalcogen defects in atomically thin MoS2(1−x)Se2x alloyscitations
- 2019On the synthesis of morphology-controlled transition metal dichalcogenides via chemical vapor deposition for electrochemical hydrogen generationcitations
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article
On the synthesis of morphology-controlled transition metal dichalcogenides via chemical vapor deposition for electrochemical hydrogen generation
Abstract
<p>Shape-engineered atomically thin transition metal dichalcogenide (TMD) crystals are highly intriguing systems with regard to both fundamental and applied science. Herein, a chemical vapor deposition-assisted generalized synthesis strategy for the triangular- and dendritic-shaped TMDs and their ternary alloys is proposed, and the TMD structures' potential for electrocatalytic hydrogen evolution reaction (HER) applications is demonstrated. The alloy formation is confirmed via micro-Raman and photoluminescence studies and further verified using transmission electron microscopy and X-ray photoelectron spectroscopy. The HER activities of MoS<sub>2</sub> and MoSe<sub>2</sub> triangles are compared with those of their dendritic structures, and an enormous improvement in terms of overpotential and current density is observed for the dendritic structures. A further enhancement of the HER activity is observed in MoS<sub>2(1−x)</sub>Se<sub>2x</sub> triangular and dendritic structures, with dendritic MoS<sub>2(1−x)</sub>Se<sub>2x</sub> providing the best activity. The demonstrated nonequilibrium growth technique opens new avenues for the synthesis of morphology-controlled, large area, complex, and atomically thin TMD structures, which can have unprecedented properties, such as the enormous catalytic activity, tunable luminescence, etc., as presented in this article.</p>