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Bente, K.
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Publications (4/4 displayed)
- 2023Broadband Air-Coupled Ultrasound Emitter and Receiver Enable Simultaneous Measurement of Thickness and Speed of Sound in Solidscitations
- 2009Microstructure of CuFeS 2–δ –CuInS 2 alloyscitations
- 2005Preparation of Cu(In,Ga)Se-2 thin film solar cells by two-stage selenization processes using N-2 gascitations
- 2005Phase correlations in the CuAlSe 2 –CuAlTe 2 systemcitations
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article
Microstructure of CuFeS 2–δ –CuInS 2 alloys
Abstract
wo series of alloys of the (CuFeS 2–δ ) 1–x (CuInS 2 ) x system with molar part of CuInS 2 x = 0.01, 0.03, 0.125, 0.25, 0.375, 0.50, 0.625, 0.75, 0.95, 0.97 and 0.99 and δ being 0 and 0.10 were prepared from the CuFeS 2–δ and CuInS 2 starting ternary compounds. The samples were investigated by micro structural optics using freshly‐polished samples and XRPD. The studies confirmed two phase coexistences with microstructures dependent on the chemical composition. The geometric‐oriented arrangement of the α‐phase with the structure of CuInS 2 is found in the (CuFeS 2–δ ) 1–x (CuInS 2 ) x system up to x equalling 0.50. It was established that the solvus of CuFeS 2–δ exceeds 0.05 molar parts of CuInS 2 , while the solvus of CuInS 2 does not exceed 0.03 molar parts of CuFeS 2–δ . Additionally, stoichiometric composition of CuFeS 2 exhibits a mixture of 3 coexisting phases of CuFeS 2–δ , with δ from 0.14 to 0.28, bornite Cu 5 FeS 4 and pyrrhotite Fe 1–x S. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)