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Korzun, Barys
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Publications (7/7 displayed)
- 2022Structure and Lattice Dynamics of Bi 1−x Nd x FeO 3 and Bi 1−x Gd x FeO 3 Ceramics near the Morphotropic Phase Boundarycitations
- 2022Structure and Lattice Dynamics of Bi1−xNdxFeO3 and Bi1−xGdxFeO3 Ceramics near the Morphotropic Phase Boundary
- 2019Magnetic Ordering of Perovskite-Like La-, Nd-, and Gd-Doped Bismuth Ferritecitations
- 2013T(x) phase diagram of the CuSbS 2 –CuInS 2 system and solubility limit of Sb in CuInS 2citations
- 2009Microstructure of CuFeS 2–δ –CuInS 2 alloyscitations
- 2009Phase relations in the CuInSe 2 –CuBiSe 2 semiconductor systemcitations
- 2005Phase correlations in the CuAlSe 2 –CuAlTe 2 systemcitations
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article
Microstructure of CuFeS 2–δ –CuInS 2 alloys
Abstract
wo series of alloys of the (CuFeS 2–δ ) 1–x (CuInS 2 ) x system with molar part of CuInS 2 x = 0.01, 0.03, 0.125, 0.25, 0.375, 0.50, 0.625, 0.75, 0.95, 0.97 and 0.99 and δ being 0 and 0.10 were prepared from the CuFeS 2–δ and CuInS 2 starting ternary compounds. The samples were investigated by micro structural optics using freshly‐polished samples and XRPD. The studies confirmed two phase coexistences with microstructures dependent on the chemical composition. The geometric‐oriented arrangement of the α‐phase with the structure of CuInS 2 is found in the (CuFeS 2–δ ) 1–x (CuInS 2 ) x system up to x equalling 0.50. It was established that the solvus of CuFeS 2–δ exceeds 0.05 molar parts of CuInS 2 , while the solvus of CuInS 2 does not exceed 0.03 molar parts of CuFeS 2–δ . Additionally, stoichiometric composition of CuFeS 2 exhibits a mixture of 3 coexisting phases of CuFeS 2–δ , with δ from 0.14 to 0.28, bornite Cu 5 FeS 4 and pyrrhotite Fe 1–x S. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)