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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Morellon, L.
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Publications (7/7 displayed)
- 2022Indium segregation in Gd-5(Si, Ge)(4) magnetocaloric materialscitations
- 2022Indium segregation in Gd-5(Si, Ge)(4) magnetocaloric materialscitations
- 2017On the nature of the (de)coupling of the magnetostructural transition in Er5Si4citations
- 20121s2p resonant inelastic x-ray scattering-magnetic circular dichroism: A sensitive probe of 3d magnetic moments using hard x-ray photonscitations
- 2009Magnetic and crystal structure of Ho-5(SixGe(1-x))(4) studied by neutron diffractioncitations
- 2005Multi-step and anomalous reproducible behaviour of the electrical resistivity near the first-order magnetostructural transition of Gd-5(Si0.1Ge0.9)(4)citations
- 2003High-coercivity ultralight transparent magnetscitations
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article
On the nature of the (de)coupling of the magnetostructural transition in Er5Si4
Abstract
In this report, a successful thermodynamical model was employed to understand the structural transition in Er5Si4, able to explain the decoupling of the magnetic and structural transition. This was achieved by DFT calculations, which were used to determine the energy differences at 0K, using a LSDA+U approximation. It was found that the M structure is the stable phase at low temperatures, as verified experimentally with a value of Delta F-0=-0.262eV. Finally, a variation of Seebeck coefficient (similar to 6 mu V) was determined at the structural transition, which allows to conclude that the electronic entropy variation is negligible in the transition. (C) 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim