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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gliemann, Hartmut
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2020Direct Synthesis of ZIF-8 on Transmission Electron Microscopy Grids Allows Structure Analysis and 3D Reconstructioncitations
- 2020ZnO@ZIF-8: Gas sensitive core-shell hetero-structures show reduced cross-sensitivity to humiditycitations
- 2019Mobility of charge carriers in self-assembled monolayerscitations
- 2018Tailoring the Strength of Nanoporous Gold by Self-Assembled Monolayers of Alkanethiolscitations
- 2018Water as a modulator in the synthesis of surface-mounted metal–organic framework films of type HKUST-1citations
- 2018Oxidative polymerization of terthiophene and a substituted thiophene monomer in metal-organic framework thin filmscitations
- 2018Surface-Anchored Metal–Organic Frameworks as Versatile Resists for Gas-Assisted E-Beam Lithography: Fabrication of Sub-10 Nanometer Structurescitations
- 2015A Photolithographic Approach to Spatially Resolved Cross-Linked Nanolayerscitations
- 2015Hierarchically Functionalized Magnetic Core/Multishell Particles and Their Postsynthetic Conversion to Polymer Capsulescitations
- 2015Peptide-equipped tobacco mosaic virus templates for selective and controllable biomineral depositioncitations
- 2015Transparent films of metal-organic frameworks for optical applicationscitations
- 2015Tunable coordinative defects in UHM-3 surface-mounted MOFs for gas adsorption and separation: A combined experimental and theoretical studycitations
- 2015Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading.citations
- 2014Nanoporous Designer Solids with Huge Lattice Constant Gradients: Multiheteroepitaxy of Metal-Organic Frameworkscitations
- 2014Fabrication of Highly Uniform Gel Coatings by the Conversion of Surface-Anchored Metal-Organic Frameworkscitations
- 2014Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separationcitations
- 2014Oriented Circular Dichroism Analysis of Chiral Surface-Anchored Metal-Organic Frameworks Grown by Liquid-Phase Epitaxy and upon Loading with Chiral Guest Compoundscitations
- 2013A mild and efficient approach to functional single-chain polymeric nanoparticles via photoinduced Diels-Alder ligationcitations
- 2013Site-selective growth of surface-anchored metal-organic frameworks on self-assembled monolayer patterns prepared by AFM nanograftingcitations
- 2013On the dielectric and optical properties of surface-anchored metal-organic frameworks: A study on epitaxially grown thin filmscitations
- 2013Systems Chemistry at marginal Interfaces
- 2013Surface anchored metal-organic frameworks as stimulus responsive antifouling coatingscitations
- 2013Post-Synthetic Modification of Metal-Organic Framework Thin Films Using Click Chemistry: The Importance of Strained C-C Triple Bondscitations
- 2012The Biocompatibility of Metal-Organic Framework Coatings: An Investigation on the Stability of SURMOFs with Regard to Water and Selected Cell Culture Mediacitations
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article
Direct Synthesis of ZIF-8 on Transmission Electron Microscopy Grids Allows Structure Analysis and 3D Reconstruction
Abstract
The first example of layer‐by‐layer growth of a metal–organic framework (MOF) directly on transmission electron microscopy (TEM) grids is described. ZIF‐8 is deposited on thin amorphous carbon films and subjected to a structure analysis by (scanning) TEM ((S)TEM). This method serves as a two‐in‐one synthesis and TEM sample‐preparation technique and allows straightforward analysis of ZIF‐8 crystallites. Artifacts resulting from sample preparation are completely avoided by this approach. The morphological properties, crystal structure, and the chemical composition of the material are investigated with high spatial resolution by a variety of methods of (analytical) electron microscopy. Furthermore, the incorporation of metallic nanoparticles in ZIF‐8 by integrating a corresponding step into the layer‐by‐layer deposition process is examined. The formation of ZIF‐8 crystals on the film proceeds as under the absence of nanoparticle‐forming synthesis steps. However, the nanoparticles rather cover the supporting amorphous carbon film than being incorporated in the ZIF‐8 material. This information cannot be obtained from standard characterization techniques but requires the application of analytical (S)TEM techniques.