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| Naji, M. |
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Hegemann, Dirk
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Topics
Publications (43/43 displayed)
- 2024Polymerization mechanisms of hexamethyldisiloxane in low-pressure plasmas involving complex geometriescitations
- 2024PVD-Beschichtungen ermöglichen textile Kabel und Sensoren: Prozesskontrolle durch angepasste Energiebereiche
- 2022Nanoporous SiOx plasma polymer films as carrier for liquid‐infused surfacescitations
- 2021Unique combination of spatial and temporal control of maleic anhydride plasma polymerizationcitations
- 2021Confined hydration in nanometer-graded plasma polymer films: insights from surface-enhanced infrared absorption spectroscopycitations
- 2021Four-dimensional imaging and free-energy analysis of sudden pore-filling events in wicking of yarnscitations
- 2020A nanolayer coating on polydimethylsiloxane surfaces enables a mechanistic study of bacterial adhesion influenced by material surface physicochemistrycitations
- 2020Plasma processing of low vapor pressure liquids to generate functional surfacescitations
- 2020How the dynamics of subsurface hydration regulates protein-surface interactionscitations
- 2018Plasma polymer film designs through the eyes of ToF-SIMScitations
- 2018Functionality and chemical stability of plasma polymer films exhibiting a vertical cross-linking gradient in their subsurfacecitations
- 2018Formation of lateral chemical gradients in plasma polymer films shielded by an inclined maskcitations
- 2018Tailored antimicrobial activity and long-term cytocompatibility of plasma polymer silver nanocompositescitations
- 2018Stable, nanometer-thick oxygen-containing plasma polymer films suited for enhanced biosensingcitations
- 2018Structural development of nanosilver on metal oxide nanofibrous membrane by plasma enhanced chemical vapor deposition (PECVD)citations
- 2018Near-surface structure of plasma polymer films affects surface behavior in water and its interaction with proteinscitations
- 2018Controlled Ag release from electrically conductive coating systemscitations
- 2018Structure and stability of C:H:O plasma polymer films co-polymerized using dimethyl carbonatecitations
- 2017Composition and stability of plasma polymer films exhibiting vertical chemical gradientscitations
- 2017Textiles: nanostructured plasma coatings
- 2017Improving the stability of amino-containing plasma polymer films in aqueous environmentscitations
- 2017Micro-patterned plasma polymer films for bio-sensingcitations
- 2016Novel approach for the development of ultra-light, fully-thermoplastic compositescitations
- 2016Deposition of functional plasma polymers influenced by reactor geometry in capacitively coupled dischargescitations
- 2016Suppression of hydrophobic recovery by plasma polymer films with vertical chemical gradientscitations
- 2016Initial growth of functional plasma polymer nanofilmscitations
- 2016Reduced protein adsorption on plasma polymer films comprising hydrophobic/hydrophilic vertical chemical gradientscitations
- 2015Long-term aging of Ag/a-C:H:O nanocomposite coatings in air and in aqueous environmentcitations
- 2015Controlling the nanostructure and stability of a-C:H:N plasma polymerscitations
- 2015Response of plasma-polymerized hexamethyldisiloxane films to aqueous environmentscitations
- 2015Deposition of plasma polymer films from acetylene and water vaporcitations
- 2015Densification and hydration of HMDSO plasma polymerscitations
- 2014Preparation of light-responsive membranes by a combined surface grafting and postmodification processcitations
- 2014Influence of deposition conditions on structure and aging of C:H:O plasma polymer films prepared from acetone/CO 2 mixturescitations
- 2013Plasma modification of man-made cellulose fibers (Lyocell) for improved fiber/matrix adhesion in poly(lactic acid) compositescitations
- 2013Sensors on textile fibres based on Ag/a-C:H:O nanocomposite coatingscitations
- 2012Tailor-made silver release properties of silver-containing functional plasma polymer coatings adjusted through a macroscopic kinetics approachcitations
- 2011Surface topography, morphology and functionality of silver containing plasma polymer nanocompositescitations
- 2011Substrate independent dyeing of synthetic textiles treated with low-pressure plasmascitations
- 2011Plasma polymerization at different positions in an asymmetric ethylene dischargecitations
- 2011Macroscopic approach to plasma polymerization using the concept of energy densitycitations
- 2010Plasma functionalization of textiles: specifics and possibilitiescitations
- 2007Multi-functional nanocomposite plasma coatings - enabling new applications in biomaterialscitations
Places of action
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article
Unique combination of spatial and temporal control of maleic anhydride plasma polymerization
Abstract
The chemical properties of plasma polymers strongly depend on the operating conditions of plasma polymerization and impact their final application. Low-pressure pulsed plasma polymerization of maleic anhydride was investigated at different positions from the glow discharge in a unique 1-m-long reactor. Based on a macroscopic approach, the growth kinetics of maleic anhydride plasma polymerization was investigated, leading to the identification of three growth regimes. The calculation of apparent activation energies associated with each regime and each position and the chemical characterization of polymer films by X-ray photoelectron spectroscopy and attenuated total reflection–Fourier-transform infrared as well as optical emission spectroscopy analyses of plasma species formed during deposition strongly indicate a combined spatial and temporal influence on the plasma polymerization kinetics.