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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pielichowski, Krzysztof
Cracow University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Thermoplastic polyurethane POSS nanohybrids: Synthesis, morphology, and biological propertiescitations
- 2023Tailoring the physical properties of non-isocyanate polyurethanes by introducing secondary amino groups along their main chaincitations
- 2020Compression-Induced Phase Transitions of Bicalutamidecitations
- 2020Measurement methodology toward determination of structure-propertyrelationships in acrylic hydrogels with starch and nanogold designed forbiomedical applicationscitations
- 2019Morphology, dynamics, and order development in a thermoplastic polyurethane with melt blended POSScitations
- 2018The effect of surface modification of microfibrillated cellulose (MFC) by acid chlorides on the structural and thermomechanical properties of biopolyamide 4.10 nanocomposites
- 2014Characterization of synthesized polyurethane/montmorillonite nanocomposites foams.citations
- 2014Effect of nanofillers on low energy impact performance of sandwich structures with nanoreinforced polyurethane foam cores.citations
- 2013Polyurethanes modified with functionalized silsesquioxane - Synthesis and propertiescitations
- 2013The Influence of Multiscale Fillers Rein forcement into Impact Resistance and Energy Absorption Properties of Polyamide 6 and Polypropylene Nanocomposite Structurescitations
- 2012Physical characteristics of nanoparticles emitted during drilling of silica based polyamide 6 nanocomposites.citations
- 2012The effect of nanoclay on dust generation during drilling process of polyamide 6 nanocompositescitations
- 2012The effect of nanoclay on dust generation during drilling of PA6 nanocomposites.citations
- 2012The Effect of Nanoclay on Dust Generation during Drilling of PA6 Nanocompositescitations
- 2007Epoxy-based fibre reinforced nanocompositescitations
- 2007Polymer/montmorillonite nanocomposites with improved thermal properties: Part I. Factors influencing thermal stability and mechanisms of thermal stability improvement.citations
Places of action
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article
Morphology, dynamics, and order development in a thermoplastic polyurethane with melt blended POSS
Abstract
<jats:title>ABSTRACT</jats:title><jats:p>A top‐down approach is applied for the production of polyurethane (PU)–polyhedral oligomeric silsesquioxane (POSS) nanocomposites, namely melt blending. As opposed to the typical chemical incorporation during synthesis, a POSS moiety with two hydroxyl groups is melt blended into a commercial thermoplastic polyurethane with mass fraction up to 2 wt %. POSS disperses in the matrix in submicrometer‐sized crystals, as well as in length scale of few tens of nanometers, in the bulk. Phase separation of the produced composites was studied by both standard dynamic and isothermal annealing experiments. In an approach rare in the literature, the dynamics of phase separation is discussed based on isothermal differential scanning calorimetry curves recorded during annealing. The blended‐in nanoparticles affect the micromorphology in a complicated manner, dependent on the intrinsically complex phase separation mechanism of PU. At higher temperatures, POSS slows down the phase separation, whereas at lower ones, it enhances and accelerates it. POSS decreases the mechanical modulus of the final material, presumably as a result of changes in the microphase separation. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. <jats:bold>2019</jats:bold>, <jats:italic>57</jats:italic>, 1133–1142</jats:p>