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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Richardson, Robert M.
University of Bristol
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2021Dendritic Micelles with Controlled Branching and Sensor Applicationscitations
- 2020Interactions between PAMAM dendrimers and DOPC lipid multilayerscitations
- 2020Interactions between PAMAM dendrimers and DOPC lipid multilayers:Membrane thinning and structural disordercitations
- 2018Structure of the Crystalline Core of Fiber-like Polythiophene Block Copolymer Micellescitations
- 2018High Stiffness Cellulose Fibers from Low Molecular Weight Microcrystalline Cellulose Solutions Using DMSO as Co-Solvent with Ionic Liquidcitations
- 2016“Cross” Supermicelles via the Hierarchical Assembly of Amphiphilic Cylindrical Triblock Comicellescitations
- 2016Blocked Shape Memory Effect in Negative Poisson's Ratio Polymer Metamaterialscitations
- 2015Self-assembly of a functional oligo(aniline)-based amphiphile into helical conductive nanowirescitations
- 2013The influence of suspended nano-particles on the frederiks threshold of the nematic host
- 2013The solution phase characterization of poly(ferrocenyldimethylsilane)s by small-angle neutron scatteringcitations
- 2013The influence of suspended nanoparticles on the Frederiks threshold of the nematic hostcitations
- 2013Electro-induced orientational ordering of anisotropic pigment nanoparticlescitations
- 2011Liquid-crystalline symmetric triblock copolymers
- 2011Probing the Structure of the Crystalline Core of Field-Aligned, Monodisperse, Cylindrical Polyisoprene-block-Polyferrocenylsilane Micelles in Solution Using Synchrotron Small- and Wide-Angle X-ray Scatteringcitations
- 2009Not All Anionic Polyelectrolytes Complex with DTAB
- 2001Carbosilane liquid crystalline dendrimers with terminal chiral mesogenic groupscitations
- 2001Polymerization of cationic surfactant phasescitations
Places of action
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article
The solution phase characterization of poly(ferrocenyldimethylsilane)s by small-angle neutron scattering
Abstract
A series of monodisperse (M-w/M-n <1.1) poly(ferrocenyldimethylsilane)s was prepared with number-averaged degrees of polymerization, z(n), of 9, 33, 206, and 506 (2-5, respectively), as determined by gel permeation chromatography (GPC). The polymers were studied by small-angle neutron scattering (SANS) in solution with the aim of obtaining the radius of gyration, R-g, the weight-averaged molecular weight, M-w, and the polydispersity index, M-w/M-n. Data were collected over the range 0.008 <Q/angstrom(-1) <0.5 and for a series of concentrations (weight fraction, w = 0.0063, 0.0125, 0.025, and 0.05). The scattered intensity, I(Q), was fitted to a model based on a Schultz-Zimm distribution of isolated chains with excluded volume. A comparison of the molecular weight and size data determined by GPC and SANS indicated an acceptable agreement between the values for R-g, M-w and M-w/M-n. The results of this study demonstrate the potential utility of SANS to fully characterize metallopolymers, and other polymer systems where traditional methods cannot be applied. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4011-4020