| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Whittaker, Michael
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2016The pharmacokinetics and biodistribution of a 64 kDa PolyPEG star polymer after subcutaneous and pulmonary administration to ratscitations
- 2015Rapid synthesis of ultrahigh molecular weight and low polydispersity polystyrene diblock copolymers by RAFT-mediated emulsion polymerizationcitations
- 2015Delivering nitric oxide with nanoparticlescitations
- 2015Molecular weight (hydrodynamic volume) dictates the systemic pharmacokinetics and tumour disposition of PolyPEG star polymerscitations
- 2014Nano-sized graphene oxide as sole surfactant in miniemulsion polymerization for nanocomposite synthesiscitations
- 2014Photoinduced sequence-control via one pot living radical polymerization of acrylatescitations
- 2012Modification of graphene/graphene oxide with polymer brushes using controlled/living radical polymerizationcitations
- 2011High-order multiblock copolymers via iterative Cu(0)-mediated radical polymerizations (SET-LRP): Toward biological precisioncitations
- 2010Synthesis of hollow polymer nanocapsules exploiting gold nanoparticles as sacrificial templatescitations
- 2009Self-assembly of well-defined amphiphilic polymeric miktoarm stars, dendrons, and dendrimers in water: The effect of architecturecitations
- 2008Synthesis of linear and 4-arm star block copolymers of poly (methyl acrylate-b-solketal aerylate) by SET-LRP at 25 Ccitations
- 2008Convergent synthesis of second generation AB-type miktoarm dendrimers using "click" chemistry catalyzed by copper wirecitations
- 2008Self-assembly of amphiphilic polymeric dendrimers synthesized with selective degradable linkagescitations
- 2007Reactive alkyne and azide solid supports to increase purity of novel polymeric stars and dendrimers via the "click" reactioncitations
- 2006Synthesis of 3-miktoarm stars and 1st generation mikto dendritic copolymers by "living" radical polymerization and "click" chemistrycitations
Places of action
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article
Synthesis of linear and 4-arm star block copolymers of poly (methyl acrylate-b-solketal aerylate) by SET-LRP at 25 C
Abstract
The new SET-LRP (using Cu(O) powder for organic synthesis) was successfully used to produce well-defined linear and star homo- and diblock-copolymers of PMA, PSA, and P(MA-D-GA)n (where n = 1 or 4). The kinetic data showed that all SET-LRP were first order and reached high conversions in a short period of time. The other advantage of using such a system is that the copper can easily be removed through filtration, allowing the production of highly pure polymer. The molecular weight distributions were well controlled with polydispersity indexes below 1.1 and the number-average molecular weight close to theory, especially upon the addition of Cu(II)Br2/Me 6-TREN complex. The linear and star block copolymers were then hydrolyzed to produce the biocompatible amphiphilic P(MA-D-GA)n, where the glycerol side-groups make the outer block hydrophilic. These blocks were micellized into water and found to have a Rg/RH equal to 0.8 and 1.59 for the liner and star blocks, respectively. This together with the TEM s supported that the linear blocks formed the classical core-shell micelles, where as, the star blocks formed vesicles. We found direct support for the vesicle structure from a TEM where one vesicle squashed a second vesicle consistent with a hollow structure. Such vesicle structures have potential applications as delivery nanoscaled devices for drugs and other important biomolecules.