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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pini, Tommaso
Sapienza University of Rome
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024A periodic micromechanical model for the rate- and temperature-dependent behavior of unidirectional carbon fiber-reinforced PVDFcitations
- 2021Deformation and failure kinetics of polyvinylidene fluoride: Influence of crystallinitycitations
- 2021Deformation and failure kinetics of polyvinylidene fluoride: Influence of crystallinitycitations
- 2019Damage mechanisms in a toughened acrylic resincitations
- 2018Fracture toughness of acrylic resinscitations
- 2018Matrix toughness transfer and fibre bridging laws in acrylic resin based CF compositescitations
- 2018Fracture toughness of acrylic resins: Viscoelastic effects and deformation mechanismscitations
- 2017Fracture initiation and propagation in unidirectional CF composites based on thermoplastic acrylic resinscitations
- 2016Time dependent fracture behaviour of a carbon fibre composite based on a (rubber toughened) acrylic polymercitations
- 2016Time dependent fracture behaviour of a carbon fibre composite based on a (rubber toughened) acrylic polymercitations
Places of action
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article
Deformation and failure kinetics of polyvinylidene fluoride: Influence of crystallinity
Abstract
The present study investigates the effect of processing conditions on the yield kinetics, such as rate dependence of the yield stress and creep rupture, of polyvinilidene fluoride. Samples were compression molded with cooling rates varying from 100°C/s to 0.5°C/min, or isothermally crystallized at temperatures varying from 20 to 120°C. Deformation kinetics were studied over a wide range of strain rates and temperatures. It is shown that for all conditions the yield response is well represented by the Ree–Eyring model. Moreover, the activation volumes and activation energies are independent from the processing conditions. The effect of processing is fully covered by a simple relationship between the rate factors and the degree of crystallinity. Subsequently, the versatility of this relationship is demonstrated by experimental validation.