| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Paluch, Marian
University of Silesia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2024The influence of molecular shape on reorientation dynamics of sizable glass-forming isomers at ambient and elevated pressurecitations
- 2024Experimental examination of dipole-dipole cross-correlations by dielectric spectroscopy, depolarized dynamic light scattering, and computer simulations of molecular dynamicscitations
- 2023Hot melt extruded posaconazole-based amorphous solid dispersions - the effect of different types of polymerscitations
- 2022Fused deposition modeling as a possible approach for the preparation of orodispersible tabletscitations
- 2022The Effect of Various Poly (N-vinylpyrrolidone) (PVP) Polymers on the Crystallization of Flutamidecitations
- 2022Studies on the Molecular Dynamics at High Pressures as a Key to Identify the Sub-Rouse Mode in PMMS
- 2022Sugar decorated star-shaped (co)polymerswith resveratrol-based core – physicochemicaland biological propertiescitations
- 2022How Does Long-Term Storage Influence the Physical Stability and Dissolution of Bicalutamide from Solid Dispersions and Minitablets?citations
- 2022Density Scaling of Translational and Rotational Molecular Dynamics in a Simple Ellipsoidal Model near the Glass Transitioncitations
- 2022Sugar decorated star-shaped (co)polymers with resveratrol-based core – physicochemical and biological propertiescitations
- 2022How does long-term storage influence the physical stability and dissolution of bicalutamide from solid dispersions and minitablets?citations
- 2021Ternary eutectic ezetimibe-simvastatin-fenofibrate system and the physical stability of Its amorphous formcitations
- 2021Impact of the chain length and topology of the acetylated oligosaccharide on the crystallization tendency of naproxen from amorphous binary mixturescitations
- 2021Comparative analysis of dielectric, shear mechanical and light scattering response functions in polar supercooled liquidscitations
- 2021Two-step aging of highly polar glasscitations
- 2021How does the addition of Kollidon®VA64 inhibit the recrystallization and improve ezetimibe dissolution from amorphous solid dispersions?citations
- 2021How to obtain the maximum properties flexibility of 3d printed ketoprofen tablets using only one drug-loaded filament?citations
- 2021Synthetic strategy matters : the study of a different kind of PVP as micellar vehicles of metronidazolecitations
- 2020Multivariate design of 3D printed immediate-release tablets with liquid crystal-forming drug—itraconazolecitations
- 2020Correlation between locally ordered (hydrogen-bonded) nanodomains and puzzling dynamics of polymethysiloxane derivativecitations
- 2020Compression-Induced Phase Transitions of Bicalutamidecitations
- 2020Pressure‐assisted strategy for the synthesis of vinyl pyrrolidone‐based macro‐star photoiniferters. A route to star block copolymerscitations
- 2020Impact of confinement on the dynamics and H-bonding pattern in low-molecular weight poly(propylene glycols)citations
- 2020Multivariate design of 3D printed immediate-release tablets with liquid crystal-forming drug - itraconazolecitations
- 2019Glassy dynamics predicted by mutual role of free and activation volumescitations
- 2019Effects of cooling rate on structural relaxation in amorphous drugs: elastically collective nonlinear langevin equation theory and machine learning studycitations
- 2018Why is the change of the Johari-Goldstein β-relaxation time by densification in ultrastable glass minor?citations
- 2018High-pressure cell for simultaneous dielectric and neutron spectroscopycitations
- 2017Dielectric relaxation and anhydrous proton conduction in [C2H5NH3][Na0.5Fe0.5(HCOO)3] metal-organic frameworkscitations
- 2017Why is surface diffusion the same in ultrastable, ordinary, aged, and ultrathin molecular glasses?citations
- 2015Ionic liquids and their bases : striking differences in the dynamic heterogeneity near the glass transitioncitations
- 2009High pressure dynamics of polymer/plasticizer mixturescitations
Places of action
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article
Pressure‐assisted strategy for the synthesis of vinyl pyrrolidone‐based macro‐star photoiniferters. A route to star block copolymers
Abstract
<jats:title>Abstract</jats:title><jats:p>Star‐shaped 1‐vinyl‐2‐pyrrolidone (VP)‐based polymers having four pendant arms were produced via high‐pressure RAFT using the trithiocarbonate‐functionalized core. The use of compression (<jats:italic>p</jats:italic> = 250 MPa) significantly reduced or eliminated star‐star/star‐chain coupling side reactions and termination process characteristics the for “<jats:italic>core‐first</jats:italic>” <jats:italic>R</jats:italic>‐type approach, still allowing for a “<jats:italic>pseudo‐living</jats:italic>” reaction course up to very high monomer conversion (>98%). Consequently, tailored and highly living star‐shaped poly(1‐vinyl‐2‐pyrrolidone)s (PVP) in a wide range of molecular weights <jats:italic>M</jats:italic><jats:sub> <jats:italic>n</jats:italic></jats:sub> = 2.0–175.6 kg/mol (<jats:italic>Đ</jats:italic> = 1.18–1.80) have been obtained. The chain extension of the produced polymer was carried out with methyl methacrylate (MMA) via photo‐induced RAFT (<jats:italic>λ</jats:italic> = 365 nm) in the presence of tertiary amine catalyst, yielding well‐defined amphiphilic star‐shaped block copolymers. DSC measurements showed that synthesized star‐shaped PVP homopolymers revealed much lower glass transition temperature values compared to their commercially supplied linear analogs.</jats:p>