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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Magalhaes, Fd
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2020Experiment and modelling of the strain-rate-dependent response during in vitro degradation of PLA fibrescitations
- 2018Dynamic mechanical analysis and creep-recovery behavior of agglomerated corkcitations
- 2018Antimicrobial graphene nanoplatelets coatings for silicone catheterscitations
- 2014Evaluation of Bonding Performance of Amino Polymers Using ABEScitations
- 2014Physicomechanical characterization of monodisperse multivesiculated polyester particlescitations
- 2013Effect of incorporation of graphene oxide and graphene nanoplatelets on mechanical and gas permeability properties of poly(lactic acid) filmscitations
- 2013Dispersion of graphene nanoplatelets in poly(vinyl acetate) latex and effect on adhesive bond strengthcitations
- 2013Preparation and Characterization of Acrylic Polymer Nanocomposite Films Obtained from Aqueous Dispersionscitations
- 2012Synthesis and Characterization of Allyl Fatty Acid Derivatives as Reactive Coalescing Agents for Latexescitations
- 2011Evaluation of urea-formaldehyde adhesives performance by recently developed mechanical testscitations
- 2010A Study on the Colloidal Nature of Urea-Formaldehyde Resins and Its Relation with Adhesive Performancecitations
- 2006New trends on membrane science
Places of action
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article
Dispersion of graphene nanoplatelets in poly(vinyl acetate) latex and effect on adhesive bond strength
Abstract
Graphene nanoplatelets (GNPs) were directly dispersed in poly(vinyl acetate) (PVAc) latex in concentrations from 0.05 up to 2 wt% (based on dry weight), without using additional surfactants or dispersants. Stable dispersions were obtained due to interaction of the GNPs with protective colloids (poly(vinyl alcohol) and hydroxyethylcellulose) originally present in the latex. This caused an increase in viscosity and accentuated the pseudoplastic behavior of the latex, as evidenced by rheological measurements. Cryo-SEM imaging showed that individual nanoplatelets were present in the aqueous phase. The equilibrium contact angle for water on dry PVAc films increased by 13 degrees upon incorporation of 0.1 wt% GNPs due to the nanofiller hydrophobicity. However, this increase was lower for higher loadings, probably due to the occurrence of GNP agglomeration. Bond strength measurements performed with an automated bonding evaluation system setup on veneer lap joints showed more than 50% shear strength increase with incorporation of only 0.10.3 wt% GNPs. At higher loadings the bond strength decreased, indicating less efficient nanofiller dispersion in the polymer matrix. Raman spectroscopy analysis confirmed that GNP agglomeration was more significant at higher loadings.