| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Tsibouklis, John
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2020Inkjet printing of a thermolabile model drug onto FDM-printed substrates: formulation and evaluationcitations
- 2015An evaluation of the adhesion of solid oral dosage form coatings to the oesophaguscitations
- 2015An evaluation of the adhesion of solid oral dosage form coatings to the oesophaguscitations
- 2013Nanocomposites based on copolymers of fluorinated imide and polyhedral oligomeric silsesquioxane macromonomer: microstructure and morphology studiescitations
- 2011Multifunctional poly(alkyl methacrylate) films for dental carecitations
- 2011Mapping surface heterogeneity: the AFM-based approach
- 2011Ring opening metathesis polymerization of polyoctahedral oligomeric silsesquioxanes (POSS) incorporated oxanorbornene-5,6-dicarboximide: synthesis, characterization, and surface morphology of copolymerscitations
- 2011The effects of incorporated silicone oils and calcium carbonate on the resistance to settlement and the antifouling performance of a silicone elastomercitations
- 2010A thermogravimetric method for assessing the substantivity of polymer films on dentally relevant substratescitations
- 2010Towards the determination of surface energy at the nanoscale: a further assessment of the AFM-based approachcitations
- 2010A comparative study of surface energy data from atomic force microscopy and from contact angle goniometrycitations
- 2008Synthesis and characterization of low surface energy fluoropolymers as potential barrier coatings in oral carecitations
- 2004Friction coefficient mapping using the atomic force microscopecitations
- 2003Ultra-low surface energy polymerscitations
- 2002Poly(di-1H,1H,2H,2H-perfluoroalkylitaconate) filmscitations
- 2002Fluoropolymer coatings with inherent resistance to biofouling
- 2002Adhesion force mapping of polymer surfaces: factors influencing force of adhesioncitations
- 2002Adsorbed poly(ethyleneoxide)–poly(propyleneoxide) copolymers on synthetic surfaces: spectroscopy and microscopy of polymer structures and effects on adhesion of skin-borne bacteriacitations
- 2002A study of pyroelectric and dielectric properties of alternate layer fluorodeconoylmonoitaconate Langmuir-Blodgett filmscitations
- 2002Impact of Fluorination and Side-Chain Length on Poly(methylpropenoxyalkylsiloxane) and Poly(alkyl methacrylate) Solubility in Supercritical Carbon Dioxidecitations
- 2002Poly(di-1H,1H,2H,2H-perfluoroalkylitaconate) films:surface organisation phenomena, surface energy determinations and force of adhesion measurementscitations
- 2001Nanoindentation and adhesion-force-mapping studies of polymer blend films
- 2000Mapping the surface heterogeneity of a polymer blend: an adhesion-force-distribution study using the Atomic Force Microscopecitations
- 2000Poly(perfluoroalkyl methacrylate) film structures: surface organization phenomena, surface energy determinations, and force of adhesion measurementscitations
Places of action
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article
Nanocomposites based on copolymers of fluorinated imide and polyhedral oligomeric silsesquioxane macromonomer: microstructure and morphology studies
Abstract
Towards the development of copolymeric nanocomposites, N-3(trifluoromethyl)phenyl-7-oxanorbornene-5,6-dicarboximide (TFI) monomer and a macromonomer of polyhedral oligomeric silsesquioxane (POSS) were synthesized. Ring-opening metathesis polymerization to copolymerization of specified proportions of the two co-monomers was carried out. All the monomers and polymers were characterized using Fourier transform IR analysis and 1H and 29Si NMR. Gel permeation chromatography shows that copolymeric nanocomposites have a lower average molar mass than a homopolymer of TFI (HTFI). TGA shows that the thermal stability of the copolymer is inversely proportional to the proportion of POSS units. DSC studies have demonstrated that the glass transition temperature (Tg) of a nanocomposite possessing 25 wt% POSS is at a higher temperature (180 °C) than that of HTFI (175 °C). Transmission electron microscopy and AFM images of copolymers are consistent with the self-assembled spherical aggregation of POSS units, while X-ray diffraction studies have confirmed the homogeneous dispersion of the same units within the nanocomposites. © 2012 Society of Chemical Industry