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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dias, Alberto R.
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article
Polymerisation of ethylene catalysed by mono-imine-2,6-diacetylpyridine iron/methylaluminoxane (MAO) catalyst system
Abstract
<p>The complex, 1-6-[(2,6-diisopropylphenyl)-ethaneimidoy1]-2-pyridinyl -1-ethanoneiron(II) dichloride (2), has been synthesised and characterised. Treatment of complex 2 with methylaluminoxane resulted in a very active catalytic system for the preparation of polyethylene (PE). The system shows activities in the order of magnitude 10<sup>7</sup> g (PE) mol<sup>-1</sup>(Fe) h<sup>-1</sup> bar<sup>-1</sup>. Characterisation by <sup>13</sup>C NMR indicated that branched PE was obtained and that experimental conditions affect polymer microstructure. PE produced contained six to eight branches per 100 carbons.</p>