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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Regazzi, Arnaud
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Recycled carbon fiber potential for reuse in carbon fiber/PA6 composite partscitations
- 2023Surface properties assessment of reclaimed carbon fibres for recycling in PA6/CF composites
- 2023Thermal conductivity of glass/talc filled Polyamide 12 as function of tapping level
- 2022Surface Energy determination of particles used as fillers in polymers: Application to lignin/PLA composites
- 2022Viscoelastic behaviour of novel thermoplastic elastomer blends for fused filament fabrication (FFF)
- 2022Fabrication of PLA/PCL/Graphene Nanoplatelet (GNP) Electrically Conductive Circuit Using the Fused Filament Fabrication (FFF) 3D Printing Techniquecitations
- 2022Laser sintering of coated polyamide 12: a new way to improve flammabilitycitations
- 2021Manufacturing of starch-based materials using ultrasonic compression moulding (UCM): toward a structural applicationcitations
- 2021Modification of poly(styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene) via free‐radical grafting and its photo‐crosslinkingcitations
- 2021Lignin as a Major Component of an Intumescent Fire Retardant System for Biopolyester
- 2021Biopolymer blends for mechanical property gradient 3D printed partscitations
- 2021Fused filament fabrication (fff) of electrically conductive pla/pcl/graphene nanoplatelets (gnp) bionanocomposites
- 2021Fused filament fabrication (fff) of electrically conductive pla/pcl/graphene nanoplatelets (gnp) bionanocomposites
- 2021Modification of poly(styrene‐<i>b</i>‐(ethylene‐<i>co</i>‐butylene)‐<i>b</i>‐styrene) via free‐radical grafting and its photo‐crosslinkingcitations
- 2020Biocomposites ignifugés pour la fabrication additive
- 20203D Printing and Mechanical Properties of Polyamide Products with Schwartz Primitive Topologycitations
- 2019Ultrasonic welding of 100% lignocellulosic paperscitations
- 2019PA 12 nanocomposites and flame retardants compositions processed through selective laser sintering
- 2019Mechanical Properties of Cellular Structures with Schwartz Primitive Topologycitations
- 2019Microstructural and mechanical properties of biocomposites made of native starch granules and wood fiberscitations
- 2015Forming Of Native Starch/Wood Composites
- 2013A contribution to the study of the coupled thermo-hydro-mechanical aging of PLA/flax biocomposites
- 2012Study Of A Coupled Mechanical-Hygrothermal Degradation Of Bio-Based Composites
Places of action
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article
Modification of poly(styrene‐<i>b</i>‐(ethylene‐<i>co</i>‐butylene)‐<i>b</i>‐styrene) via free‐radical grafting and its photo‐crosslinking
Abstract
<jats:title>Abstract</jats:title><jats:p>Poly(styrene‐<jats:italic>b</jats:italic>‐(ethylene‐<jats:italic>co</jats:italic>‐butylene)‐<jats:italic>b</jats:italic>‐styrene) (SEBS) is functionalized via radical grafting with 4‐vinyl‐1‐cyclohexene 1,2‐epoxide (VCHO) initiated using 2,5‐Bis(tert‐butylperoxy)‐2,5‐dimethylhexane. The existence of the epoxide group on the SEBS backbone is evidenced by <jats:sup>1</jats:sup>H nuclear magnetic resonance. A size exclusion chromatography (SEC) study reveals some chain coupling, and this phenomenon is limited by controlling the quantities of peroxide and monomer reagents used during the radical grafting. Photo‐crosslinking of SEBS‐<jats:italic>g</jats:italic>‐VCHO under ultraviolet irradiation in the presence of a cationic initiator is then successfully performed with resultant gel contents higher than 85%. Mechanical properties of SEBS and crosslinked materials are measured by tensile tests on thin films. On the one hand, those tests reveal a significant increase of Young's modulus of the crosslinked materials. On the other hand, the diminution of elongation at break is much more limited; crosslinked materials retain their elastomeric properties with an elongation at break greater than 200%. Finally, the photosensitive SEBS‐<jats:italic>g</jats:italic>‐VCHO is used to show the adhesion performance of the photo‐crosslinking coating as well as a resin for the stereolithography process.</jats:p>