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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tiwari, Atul
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2015Sol-Gel Route for the Development of Smart Green Conversion Coatings for Corrosion Protection of Metal Alloyscitations
- 2014Nanoindentation and morphological analysis of novel green quasi-ceramic nanocoating materialscitations
- 2014Cumulative release of cefotaxim from interpenetrating networks of poly(vinyl alcohol- g -acrylamide) and chitosan- g -polyacrylamide chainscitations
- 2012Effect of inorganic constituent on nanomechanical and tribological properties of polymer, quasi-ceramic and hybrid coatingscitations
- 2010High performance reaction-induced quasi-ceramic silicone conversion coating for corrosion protection of aluminium alloyscitations
- 2008The development of low-temperature hardening silicone ceramer coatings for the corrosion protection of metalscitations
- 2006Analysis of molecular morphology and permeation behavior of polyimide-siloxane molecular composites for their possible coatings applicationcitations
- 2004Thermal analysis of polysiloxanes, aromatic polyimide and their blendscitations
- 2004In situ generated diphenylsiloxane-polyimide adduct-based nanocompositescitations
- 2004Encapsulation of air‐filled poly(dimethylsiloxane) microballoons in polyimide as a polymeric low ε dielectriccitations
- 2003Synthesis, characterization, physicochemical and dielectric properties of siloxane, polyimide and their blendscitations
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article
In situ generated diphenylsiloxane-polyimide adduct-based nanocomposites
Abstract
Arylsiloxane was incorporated into polyimide (PI) via electronic interaction with polyamic acid (PAA)/PI, and a wide spectrum of properties were evaluated for different compositions. The samples prepared with relatively low concentrations (0.0001–0.1%) of oligomers showed unusual synergism, which is attributed to the generation of nanostructures dispersed in the continuous PI matrix. The incorporation of siloxane with bulky phenyl groups contributed to enhanced thermal stability as determined by thermogravimetric analysis. Water uptake and methanol absorption by these composites were evaluated and correlated with the underlying micro- and nanostructures. Fourier Transform Infrared (FTIR) spectroscopy was used to elucidate the probable reaction mechanism (including in situ polymerization of arylsilanol), and to study the synthetic aspects associated with the molecular composites and nanocomposites formation. POLYM. ENG. SCI., 45:142–152, 2005. © 2004 Society of Plastics Engineers