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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cunha, A. M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (55/55 displayed)
- 2010Thermomechanical processing environment and morphology development of a thermotropic polymer liquid crystalcitations
- 2010Effect of surface treatment in cork reinforced compositescitations
- 2010Residual stresses in gas-assisted injection molding.citations
- 2010Thermoresponsive self-assembled elastin-based nanoparticles for delivery of BMPscitations
- 2008Biodegradable composites applied to the automotive industry: the development of a loudspeaker front
- 2006Influence of the interaction potential parameters on the mechanical response of simulated semi-crystalline polymeric materialscitations
- 2006Fiber orientation in divergent/convergent fows in expansion and compression injection moldingcitations
- 2005Processing and characterization of biodegradable soy plastics: Effects of crosslinking with glyoxal and thermal treatmentcitations
- 2004Controlled delivery achieved with bi-layer matrix devices produced by co-injection mouldingcitations
- 2004Integrated compounding and injection moulding of short fibre reinforced compositescitations
- 2004pH-sensitive soy protein films for the controlled release of an anti-inflammatory drug
- 2003Shear controlled orientation in injection moulding of starch based blends intended for medical applications
- 2003In vitro degradation behaviour of biodegradable soy plastics : effects of crosslinking with glyoxal and thermal treatmentcitations
- 2003In vitro degradation behaviour of biodegradable soy plastics : effects of crosslinking with glyoxal and thermal treatmentcitations
- 2003Development and design of double-layer co-injection moulded soy protein based drug delivery devicescitations
- 2003Bi-composite sandwich moldings: processing, mechanical performance and bioactive behaviourcitations
- 2003Development and design of novel co-injection molded soy protein delivery devices
- 2003Structural development of HDPE in injection moldingcitations
- 2003Casein and soybean protein-based thermoplastics and composites as alternative biodegradable polymers for biomedical applications
- 2003Soy matrix drug delivery systems obtained by melt-processing techniquescitations
- 2003Coupling of HDPE/hydroxyapatite composites by silane-based methodologiescitations
- 2003Plasma- and chemical-induced graft polymerization on the surface of starch-based biomaterials aimed at improving cell adhesion and proliferationcitations
- 2003In vitro degradation and cytocompatibility evaluation of novel soy and sodium caseinate-based membrane biomaterialscitations
- 2003Bi-composite sandwich moldingscitations
- 2003Effect of crosslinking, thermal treatment and UV irradiation on the mechanical properties and in vitro degradation behavior of several natural proteins aimed to be used in the biomedical fieldcitations
- 2003Processing and properties of bone-analogue biodegradable and bioinert polymeric compositescitations
- 2003In vitro degradation behaviour of biodegradable soy plastics: effects of crosslinking with glyoxal and thermal treatmentcitations
- 2002Bi-composite sandwich injection moulding: A new method of producing stiff and strongly bioactive bone-analogues
- 2002Use of coupling agents to enhance the interfacial interactions in starch-EVOH/hydroxylapatite compositescitations
- 2002Mechanical behaviour of polyethylene/hydroxyapatite bone-analogue composites moulded with an induced anisotropy
- 2002Dynamic mechanical analysis in polymers for medical applications
- 2002Novel starch thermoplastic/Bioglass® composites: Mechanical properties, degradation behavior and in-vitro bioactivitycitations
- 2002Mechanical performance of starch based bioactive composite biomaterials molded with preferred orientationcitations
- 2002Performance of chromium nitride and titanium nitride coatings during plastic injection mouldingcitations
- 2002Reinforcement and structure development in injection molding of bone-analogue composites
- 2002Design and processing of starch based scaffolds for hard tissue engineering
- 2002Structure development and interfacial interactions in high-density polyethylene/hydroxyapatite (HDPE/HA) composites molded with preferred orientationcitations
- 2002Alternative tissue engineering scaffolds based on starch: processing methodologies, morphology, degradation and mechanical propertiescitations
- 2001A new approach based on injection moulding to produce biodegradable starch-based polymeric scaffolds: morphology, mechanical and degradation behaviourcitations
- 2001Biocompatibility testing of novel starch-based materials with potential application in orthopaedic surgery: a preliminary studycitations
- 2001Cytocompatibility and response of osteoblastic-like cells to starch-based polymers: effect of several additives and processing conditionscitations
- 2001Development of highly bioactive and mechanically strong starch thermoplastic/bioglass composite biomaterials
- 2001Structure and properties of hydroxylapatite reinforced starch bone-analogue composites
- 2001In-vitro degradation behaviour of starch/EVOH biomaterialscitations
- 2001Viscoelastic behaviour and time-temperature correspondence of HDPE with varying levels of process-induced orientationcitations
- 2001Degradation model of starch-EVOH+HA compositescitations
- 2001Relationship between processing and mechanical properties of injection molded high molecular mass polyethylene + hydroxyapatite compositescitations
- 2001Relationship between processing and mechanical properties of injection molded high molecular mass polyethylene plus hydroxyapatite compositescitations
- 2000Chemical modification of starch based biodegradable polymeric blends: effects on water uptake, degradation behaviour and mechanical propertiescitations
- 2000Effects of moisture and degradation time over the mechanical dynamical performance of starch-based biomaterials
- 2000Performance of chromium nitride based coatings under plastic processing conditionscitations
- 2000Development of highly bioactive and mechanically strong starch thermoplastic/Bioglass (R) composite biomaterials
- 2000Injection molding of a starch/EVOH blend aimed as an alternative biomaterial for temporary applications
- 2000Prediction of mechanical properties of polyethylene mouldings based on laminate theory and thermomechanical indices
- 2000Structure and properties of hydroxylapatite reinforced starch bone-analogue composites
Places of action
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article
Mechanical performance of starch based bioactive composite biomaterials molded with preferred orientation
Abstract
Composites of blends of starch with ethylene vinyl alcohol copolymer (SEVA-C) filled with 10, 30 and 50% by weight (wt.) of hydroxyapatite (HA–the major inorganic constituent of human bone) were produced by twin-screw extrusion (TSE) compounding. These composites were molded into tensile test bars using two molding techniques: i) conventional injection molding and ii) shear controlled orientation in injection molding (SCORIM). The bars produced were mechanically characterized by means of tensile testing and dynamical mechanical analysis (DMA). The structure of the moldings was assessed by wide-angle X-ray diffraction (WAXD) and the failure surfaces of the moldings analyzed by scanning electron microscopy (SEM). The enhancement of stiffness observed with HA reinforcement results partially from the stiffening effect of the blend associated with the decrease in plasticizer content during the compounding stage. SCORIM was able to further increase the stiffness of SEVA-C/HA composites, allowing a maximum improvement of 12% for 30% wt. HA as compared to conventional molding. DMA results showed that the reinforcement of SEVA-C causes the broadening of the relaxation peak of the polymer, suggesting a structural change within the starch fraction that may be related with thermal degradation of the polymer. The addition of HA particles reduces the preferred orientation exhibited by the SEVA-C matrix, which is believed to limit the maximum mechanical performance that can be attained. Nevertheless, composites based on a biodegradable matrix with modulus above 7 GPa (in the bounds of the lower limit for human cortical bone) could be successfully produced.