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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Marciniak, Piotr
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2022Carbonate Lake Sediments in the Plastics Processing-Preliminary Polylactide Composite Case Study: Mechanical and Structural Propertiescitations
- 2021Sol-Gel Approach for Design of Pt/Al2O3-TiO2 System-Synthesis and Catalytic Testscitations
- 2021Metallic Calcium as a Precursor for Sol-Gel Synthesis of CaCO3-SiO2 and CaO-SiO2 Systemscitations
- 2020Highly bulky spherosilicates as functional additives for polyethylene processing--Influence on mechanical and thermal propertiescitations
- 2019One-pot synthesis method of SiO2-La2O2CO3 and SiO2-La2O3 systems using metallic lanthanum as a precursorcitations
- 2018One-pot synthesis of Al2O3-La2O2CO3 systems obtained from the metallic precursor by the sol-gel methodcitations
- 2018New method for the synthesis of Al2O3–CaO and Al2O3–CaO–CaCO3 systems from a metallic precursor by the sol–gel routecitations
- 2004Effect of Temperature on textural and structural behaviour of Al2O3-GeO2 and Al2O3-SnO2 sol-gel systems
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article
Highly bulky spherosilicates as functional additives for polyethylene processing--Influence on mechanical and thermal properties
Abstract
In this work, a series of cage siloxanes (spherosilicate [SS] type) was tested as functional additives for preparation of polyethylene (PE)-based nanocomposites. For this purpose, the compounds were prepared by condensation and olefin hydrosilylation reactions. The effect of these products on properties of obtained nanocomposites was analyzed by means of mechanical, microscopic (scanning electron microscopy-energy dispersive spectroscopy), crystallographic (X-ray diffraction), thermal (differential scanning calorimetry, thermogravimetry), rheological Melt flow rate (MFR), and thermomechanical (heat deflection temperature) analyses. The results were compared with similar reports on silsesquioxane- and SS-reinforced PE systems. Effects of SS functional group structure on the behavior of the additive and properties of the composite system were discussed. Aspects of thermal decomposition of PE-containing SS were studied and a probable mechanism of these polymer systems degradation was proposed. © 2020 Society of Plastics Engineers