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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Marciniec, Bogdan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Preparation and Characterization of Composites Based on ABS Modified with Polysiloxane Derivativescitations
- 2024Enhancing the Thermal Resistance of UV-Curable Resin Using (3-Thiopropyl)polysilsesquioxanecitations
- 2022New Ceramics Precursors Containing Si and Ge Atoms—Cubic Germasilsesquioxanes—Synthesis, Thermal Decomposition and Spectroscopic Analysiscitations
- 2022Where ppm Quantities of Silsesquioxanes Make a Difference—Silanes and Cage Siloxanes as TiO<inf>2</inf> Dispersants and Stabilizers for Pigmented Epoxy Resinscitations
- 2021Why POSS-Type Compounds Should Be Considered Nanomodifiers, Not Nanofillers—A Polypropylene Blends Case Studycitations
- 2020Highly bulky spherosilicates as functional additives for polyethylene processing--Influence on mechanical and thermal propertiescitations
- 2019Synthetic routes to silsesquioxane-based systems as photoactive materials and their precursorscitations
- 2019The influence of surface physicochemistry of solid fillers on dispersion in polyurea systems
- 2018Interfacial interactions in PTT–PTMO/polyhedral oligomeric silsesquioxane (POSS) nanocomposites and their impact on mechanical, thermal, and dielectric propertiescitations
- 2017Copolymers of ethylene with monoalkenyl- and monoalkenyl(siloxy)silsesquioxane (POSS) comonomers – Synthesis and characterizationcitations
- 2017Dynamic Heterogeneity in Random Copolymers of Polymethacrylates Bearing Different Polyhedral Oligomeric Silsesquioxane Moieties (POSS)citations
- 2015Polymethacrylates with polyhedral oligomeric silsesquioxane (POSS) moieties: Influence of spacer length on packing, thermodynamics, and dynamicscitations
- 2015Morphology and phase separation in PTT-block-PTMO nanocomposites containing POSS particlescitations
- 2013Polyurethanes modified with functionalized silsesquioxane - Synthesis and propertiescitations
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article
Highly bulky spherosilicates as functional additives for polyethylene processing--Influence on mechanical and thermal properties
Abstract
In this work, a series of cage siloxanes (spherosilicate [SS] type) was tested as functional additives for preparation of polyethylene (PE)-based nanocomposites. For this purpose, the compounds were prepared by condensation and olefin hydrosilylation reactions. The effect of these products on properties of obtained nanocomposites was analyzed by means of mechanical, microscopic (scanning electron microscopy-energy dispersive spectroscopy), crystallographic (X-ray diffraction), thermal (differential scanning calorimetry, thermogravimetry), rheological Melt flow rate (MFR), and thermomechanical (heat deflection temperature) analyses. The results were compared with similar reports on silsesquioxane- and SS-reinforced PE systems. Effects of SS functional group structure on the behavior of the additive and properties of the composite system were discussed. Aspects of thermal decomposition of PE-containing SS were studied and a probable mechanism of these polymer systems degradation was proposed. © 2020 Society of Plastics Engineers