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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Picken, S. J.
Delft University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Role of Molecular Water Layer State on Freezing Front Propagation Rate and Mode Studied with Thermal Imagingcitations
- 2023Affine Deformation and Self-Assembly Alignment in Hydrogel Nanocomposites
- 2023Affine Deformation and Self-Assembly Alignment in Hydrogel Nanocomposites
- 2023Enhancing the sensitivity of silicon photonic ultrasound sensors by optimizing the stiffness of polymer cladding
- 2022Extraction of low molecular weight polyhydroxyalkanoates from mixed microbial cultures using bio-based solventscitations
- 2022High-Strength Liquid Crystal Polymer-Graphene Oxide Nanocomposites from Watercitations
- 2016Water Sorption and Diffusion in (Reduced) Graphene Oxide-Alginate Biopolymer Nanocompositescitations
- 2016Composition dependent properties of graphene (oxide)-alginate biopolymer nanocompositescitations
- 2016Rheological investigation of specific interactions in Na Alginate and Na MMT suspensioncitations
- 2015Origin of highly ordered sodium alginate/montmorillonite bionanocompositescitations
- 2013Self-healing supramolecular polymer nanocomposites
- 2011Three-phase Lewis-Nielsen model for the thermal conductivity of polymer nanocompositescitations
- 2009Thermal behaviour of epoxy resin filled with high thermal conductivity nanopowderscitations
- 2007Vapor diffusion in porous/nonporous polymer coatings by dielectric sorption analysiscitations
- 2005Multiple glass transitions in the plastic crystal phase of triphenylene derivatescitations
- 2000Highly ordered side-chain liquid-crystalline polymers from maleic anhydride and swallow-tailed 1-alkenes having two mesogens
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article
Composition dependent properties of graphene (oxide)-alginate biopolymer nanocomposites
Abstract
<p>We report on the thermal, electrical, and mechanical properties of alginate biopolymer nanocomposites prepared by solution casting with various amounts of graphene oxide (GO) or reduced GO (rGO). Our data shows that the thermal stability of alginate nanocomposites can be improved by the introduction of cross-linking through divalent metal cations, albeit that under these conditions little influence by the amount of rGO remains. On the other hand, the electrical conductivity of divalent metal ion cross-linked-rGO improves approximately 10 orders of magnitude with increasing weight fraction of rGO, whereas it declines for sodium alginate-GO composites. In addition, storage moduli and glass to rubber transition temperatures show strong composition dependence as a consequence of complex interactions of the ions with both polymer and filler. We propose a mechanical model that allows for the accurate prediction of reinforcement by GO sheets in sodium alginate-GO composites taking into account the orientational order of the sheets. Creep tests reveal the complex nature of multiple stress relaxation mechanisms in the nanocomposites although the stretched exponential Burgers' model accurately describes short time creep compliance.</p>