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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ioanid, Aurelia
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article
Composite materials based on polydimethylsiloxane and <i>in situ</i> generated silica by using the sol–gel technique
Abstract
<jats:title>Abstract</jats:title><jats:p>A polydimethylsiloxane‐α,ω‐diol with molar mass <jats:italic>M</jats:italic><jats:sub>n</jats:sub> = 43,000 has been synthesized by cationic polymerization of octamethylcyclotetrasiloxane and reinforced with silica. Two pathways were used for incorporation of silica in the polymeric matrix: <jats:italic>ex situ</jats:italic> by mechanical blending of a pretreated fumed silica and <jats:italic>in situ</jats:italic> by adding tetraethyl‐orthosilicate (TEOS) as silica precursor in the polymer matrix followed by their hydrolysis and condensation (sol–gel technique). The procedure occurred in the absence of solvent. Composites with different contents of silica were prepared and investigated by dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). The results were compared to those obtained on a model network based on the same polysiloxane without silica. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers</jats:p>